Synthesis and characterization of aryltriphenylsilyl ethers and crystal structure of 2,4,6-tri-methylphenyl triphenylsilyl ether
Küçük Resim Yok
Tarih
2013
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Synthesis and structures of aryl triphenylsilyl ether derivatives are reported. Reactions of chlorotriphenylsilane, (C6H5)(3)SiCl (1), with sodium salts of sterically hindered phenol derivatives (2a-2i) were investigated. Aryltriphenylsilyl ethers (C6H5)(3)SiOAr (3-8) were obtained from these reactions. Structures of 3-8 were defined by IR, H-1, C-13, Si-29 NMR spectroscopy, elemental analysis, and ESI-MS spectra. The molecular structure of 2,4,6-tri-methylphenyl triphenylsilyl ether (6) were determined by single-crystal X-ray diffraction.
Açıklama
Anahtar Kelimeler
Aryltriphenylsilyl ether, Chlorotriphenylsilane, Si-29 NMR, Phenol
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
66
Sayı
8
