Crystallization activation energy and hole concentration properties of the Bi2Sr2Ca1-xCdxCu2O8+y glass-ceramic superconductor rods

Küçük Resim Yok

Tarih

2002

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Kluwer Academic/Plenum Publ

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The glass rods with the nominal compositions of Bi2Sr2Ca1-xCdxCu2O8+y, where x = 0.0, 0.4, and 0.8, were prepared by melt-casting method. XRD studies exhibited that the Cd substitution caused a transition from Bi-2212 phase to Bi-2201 phase. The multiphase structure was obtained for higher Cd concentration cases. It was determined that the activation energy for crystallization was decreased with the increase of the Cd concentration. When the Cd concentration was increased in the system the superconducting properties decreased. The hole concentration, p, was calculated using the Presland's method. The increase in the Cd concentration increased the hole concentration and the results showed that the Cd-substituted samples were highly in the overdoped region.

Açıklama

Anahtar Kelimeler

glass-ceramic BSCCO system, crystallization activation energy, hole concentration

Kaynak

Journal of Superconductivity

WoS Q Değeri

Q3

Scopus Q Değeri

Cilt

15

Sayı

6

Künye