THE 1ST NEUTRAL, MONONUCLEAR 4F METAL THIOLATES AND NEW METHODS FOR CORRESPONDING ARYL OXIDES AND BIS(TRIMETHYLSILYL)AMIDES

dc.authoridSmith, Richard/0000-0001-9254-941X
dc.authoridSmith, Richard/0000-0001-5894-4600
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorCETINKAYA, B
dc.contributor.authorHITCHCOCK, PB
dc.contributor.authorLAPPERT, MF
dc.contributor.authorSMITH, RG
dc.date.accessioned2024-08-04T21:01:18Z
dc.date.available2024-08-04T21:01:18Z
dc.date.issued1992
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe first neutral, mononuclear 4f metal thiolates, [Sm(SAr)3] 1 and [Yb(SAr)2(dme)2]2, have been prepared and X-ray characterised [< Sm-S > 2.645(9) angstrom, < Yb-S > 2.756(8) angstrom], 1 from [Sm(CHR'2)3] + 3ArSH and 2 from [Yb(NR'2)2(dme)2] [obtained from Yb + Sn(NR'2)2]; 1 was not readily accessible from ArSH and Yb in liquid NH3, although replacing ArSH by Ar'OH yielded [Yb(OAr')2(thf)3] [Ar = C6H2But3-2,4,6; Ar' = C6H2But2-2,6-Me-4; R' = SiMe3, dme = (MeOCH2)2, thf = OC4H8].en_US
dc.identifier.endpage934en_US
dc.identifier.issn0022-4936
dc.identifier.issue13en_US
dc.identifier.startpage932en_US
dc.identifier.urihttps://hdl.handle.net/11616/104272
dc.identifier.wosWOS:A1992JB04600007en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofJournal of The Chemical Society-Chemical Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRay Crystal-Structureen_US
dc.subjectDivalent Lanthanoid Synthesisen_US
dc.subject(Pentamethylcyclopentadienyl)Dithiocarbamato Derivativesen_US
dc.subjectLiquid-Ammoniaen_US
dc.subjectComplexesen_US
dc.subjectBis(Pentamethylcyclopentadienyl)(Diethyldithiocarbamato)Ytterbium(Iii)en_US
dc.subjectBis(Pentamethylcyclopentadienyl)Carboxylatoen_US
dc.subjectNeodymium(Iii)en_US
dc.subjectYtterbium(Iii)en_US
dc.subjectChemistryen_US
dc.titleTHE 1ST NEUTRAL, MONONUCLEAR 4F METAL THIOLATES AND NEW METHODS FOR CORRESPONDING ARYL OXIDES AND BIS(TRIMETHYLSILYL)AMIDESen_US
dc.typeArticleen_US

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