THE 1ST NEUTRAL, MONONUCLEAR 4F METAL THIOLATES AND NEW METHODS FOR CORRESPONDING ARYL OXIDES AND BIS(TRIMETHYLSILYL)AMIDES
dc.authorid | Smith, Richard/0000-0001-9254-941X | |
dc.authorid | Smith, Richard/0000-0001-5894-4600 | |
dc.authorid | Cetinkaya, Bekir/0000-0002-4551-8650 | |
dc.contributor.author | CETINKAYA, B | |
dc.contributor.author | HITCHCOCK, PB | |
dc.contributor.author | LAPPERT, MF | |
dc.contributor.author | SMITH, RG | |
dc.date.accessioned | 2024-08-04T21:01:18Z | |
dc.date.available | 2024-08-04T21:01:18Z | |
dc.date.issued | 1992 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | The first neutral, mononuclear 4f metal thiolates, [Sm(SAr)3] 1 and [Yb(SAr)2(dme)2]2, have been prepared and X-ray characterised [< Sm-S > 2.645(9) angstrom, < Yb-S > 2.756(8) angstrom], 1 from [Sm(CHR'2)3] + 3ArSH and 2 from [Yb(NR'2)2(dme)2] [obtained from Yb + Sn(NR'2)2]; 1 was not readily accessible from ArSH and Yb in liquid NH3, although replacing ArSH by Ar'OH yielded [Yb(OAr')2(thf)3] [Ar = C6H2But3-2,4,6; Ar' = C6H2But2-2,6-Me-4; R' = SiMe3, dme = (MeOCH2)2, thf = OC4H8]. | en_US |
dc.identifier.endpage | 934 | en_US |
dc.identifier.issn | 0022-4936 | |
dc.identifier.issue | 13 | en_US |
dc.identifier.startpage | 932 | en_US |
dc.identifier.uri | https://hdl.handle.net/11616/104272 | |
dc.identifier.wos | WOS:A1992JB04600007 | en_US |
dc.identifier.wosquality | N/A | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.language.iso | en | en_US |
dc.publisher | Royal Soc Chemistry | en_US |
dc.relation.ispartof | Journal of The Chemical Society-Chemical Communications | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Ray Crystal-Structure | en_US |
dc.subject | Divalent Lanthanoid Synthesis | en_US |
dc.subject | (Pentamethylcyclopentadienyl)Dithiocarbamato Derivatives | en_US |
dc.subject | Liquid-Ammonia | en_US |
dc.subject | Complexes | en_US |
dc.subject | Bis(Pentamethylcyclopentadienyl)(Diethyldithiocarbamato)Ytterbium(Iii) | en_US |
dc.subject | Bis(Pentamethylcyclopentadienyl)Carboxylato | en_US |
dc.subject | Neodymium(Iii) | en_US |
dc.subject | Ytterbium(Iii) | en_US |
dc.subject | Chemistry | en_US |
dc.title | THE 1ST NEUTRAL, MONONUCLEAR 4F METAL THIOLATES AND NEW METHODS FOR CORRESPONDING ARYL OXIDES AND BIS(TRIMETHYLSILYL)AMIDES | en_US |
dc.type | Article | en_US |