CARBENE COMPLEXES .24. PREPARATION AND CHARACTERIZATION OF 2 ENETETRAMINE-DERIVED CARBENERHODIUM(I) CHLORIDE COMPLEXES RHCL(L(R))(3) AND [RHCL(COD)L(R)] (L(R)=CN(ME)C(CH)(4)CNME-O) AND THE PREPARATION AND X-RAY STRUCTURES OF THE ENETETRAMINE L(2)(R) AND ITS SALT [L(2)(R)][BF4](2) (VOL 481, PG 89, 1994)

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dc.authoridKUCUKBAY, HASAN/0000-0002-7180-9486
dc.authorwosidKUCUKBAY, HASAN/A-5050-2019
dc.contributor.authorCETINKAYA, E
dc.contributor.authorHITCHCOCK, PB
dc.contributor.authorKUCUKBAY, H
dc.contributor.authorLAPPERT, MF
dc.contributor.authorALJUAID, S
dc.date.accessioned2024-08-04T20:57:19Z
dc.date.available2024-08-04T20:57:19Z
dc.date.issued1995
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe enetetramine [o-C6H4{N(Me)}C-2](2) (abbreviated as L(2)(R)) (1) has been obtained either from N,N'-dimethyl-o-phenylenediamine and CH(OMe)(2)NMe(2) or from [o-C6H4{N(Me)}C-2]I and NaH. Treatment of 1 with Ag[BF4] yielded the salt [L(2)(R)][BF4](2) (2). Use of L(2)(R) and [{Rh(mu-Cl)(COD)}(2)] in appropriate stoichiometry gave the carbenerhodium(I) chlorides [RhCl(COD)L(R) and RhCl(L(R))(3); Rh-103 NMR chemical shifts for 3 and 4 have been recorded. Crystal structure determinations were carried out on compounds 1 and 2. The most notable features are the differences between 1 and 2 with respect to (i) the C-C bond length [1.344(4) Angstrom (1) and 1.462(13) Angstrom (2)], (ii) the adjacent endocyclic N-C bond length [1.428(8) Angstrom (1) and 1.331(4) Angstrom (2)], (iii) the torsion angle about the central C-C bond [21 degrees (1) and 72 degrees (2)] and (iv) the closer approach of the nitrogen environment to trigonal planar in 2 than in 1.en_US
dc.identifier.doi10.1016/0022-328X(94)05390-W
dc.identifier.endpageC7en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue1-2en_US
dc.identifier.startpageC7en_US
dc.identifier.urihttps://doi.org/10.1016/0022-328X(94)05390-W
dc.identifier.urihttps://hdl.handle.net/11616/102531
dc.identifier.volume491en_US
dc.identifier.wosWOS:A1995QN89000039en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryDiğeren_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRHODIUMen_US
dc.subjectCARBENEen_US
dc.subjectCRYSTAL STRUCTUREen_US
dc.subjectENETETRAMINEen_US
dc.titleCARBENE COMPLEXES .24. PREPARATION AND CHARACTERIZATION OF 2 ENETETRAMINE-DERIVED CARBENERHODIUM(I) CHLORIDE COMPLEXES RHCL(L(R))(3) AND [RHCL(COD)L(R)] (L(R)=CN(ME)C(CH)(4)CNME-O) AND THE PREPARATION AND X-RAY STRUCTURES OF THE ENETETRAMINE L(2)(R) AND ITS SALT [L(2)(R)][BF4](2) (VOL 481, PG 89, 1994)en_US
dc.typeCorrectionen_US

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