1,4,5,6-tetrahyropyrimidinium halides ligands for Suzuki-Miyaura cross-coupling of unactivated aryl chlorides
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Four functionalized bis(1,4,5,6-tetrahyropyrimidinium) salts (2a-d) have been prepared and characterized by conventional spectroscopic methods and elemental analyses. A highly effective, easy to handle and environmentally benign process for palladium mediated Suzuki cross-coupling was developed. The in situ prepared three component system Pd(OAC)(2) / bis(1,4,5,6-tetrahyropyrimidinium) bromides (2a-d) and CS2CO3 catalyses quantitatively the Suzuki cross-coupling of deactivated aryl chloride.
Açıklama
Anahtar Kelimeler
N-Heterocarbene Ligands, Highly-Active Catalyst, Heterocyclic Carbenes, Palladium Catalysts, Aqueous-Media, Amination, Complex
Kaynak
Heterocycles
WoS Q Değeri
Q3
Scopus Q Değeri
Cilt
65
Sayı
6
