Polyimides from a novel monomer 3,6-bis(dimethylamino) acridine(p-cymene)dichlororuthenium(II) for a catalytic application

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorSeckin, T
dc.contributor.authorKoytepe, S
dc.contributor.authorÖzdemir, I
dc.contributor.authorGürbüz, N
dc.contributor.authorÇetinkaya, B
dc.date.accessioned2024-08-04T21:00:10Z
dc.date.available2024-08-04T21:00:10Z
dc.date.issued2004
dc.departmentİnönü Üniversitesien_US
dc.description.abstractTricyclic heteroaraomatic dye-based monomer containing NMe2 units, 6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium (II), was used to prepare novel polyimides via a one-stage solution polycondensation due to their stability under a variety of oxidative and reductive conditions. The Ru(II) complex monomer was synthesized starting from [RuCl2(p-cymene)](2) and 3,6-bis(dimethylamino)acridine. A series of stable polyimides was synthesized from the Ru(II) complex of 3,6-bis(dimethylamino)acridine and various aromatic dianhyrides. The polymers had inherent viscosities ranging from 1.72 to 2.11 dL/g and were soluble in polar solvents. The glass transition temperatures were 192-278degreesC, and the 10% weight loss temperatures were above 503-635degreesC. Ruthenium-substituted polyimides were tested for catalytic activity in the furan formation reaction of (Z)-3-methylpent-2-en-4-yn-1-ol. The polymeric catalyst was added to (Z)-3-methylpent-2-en-4-yn-1-ol without a solvent and the pure furan was isolated by distillation under reduced pressure. The conversion of the starting, enynol, was determined by gas chromatography (GC).en_US
dc.identifier.doi10.1023/B:JOIP.0000039366.65792.68
dc.identifier.endpage190en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue3en_US
dc.identifier.startpage177en_US
dc.identifier.urihttps://doi.org/10.1023/B:JOIP.0000039366.65792.68
dc.identifier.urihttps://hdl.handle.net/11616/103865
dc.identifier.volume14en_US
dc.identifier.wosWOS:000223516000003en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpolyimideen_US
dc.subjectthermally stable polymersen_US
dc.subjectcatalysten_US
dc.subjectruthenium(II) complexen_US
dc.subjectfuran formation reactionen_US
dc.titlePolyimides from a novel monomer 3,6-bis(dimethylamino) acridine(p-cymene)dichlororuthenium(II) for a catalytic applicationen_US
dc.typeArticleen_US

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