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Öğe Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene(Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 2018) Karaca, HüseyinÖz: Cobalt (II) phthalocyanines carrying on the four of the peripheral positions furan and thiophene as chalcones were sythesized. THF is used to investigate the catalytic oxidation of 2-mercaptoethanol. The synthesized phthalocyanines show catalytic activity on the oxidation of 2-mercaptoethanol. Cobalt (II) phthalocyanine derived by chalcone with furan has given catalytic specifications such as turnover number TON as 16.6, initial reaction rate as 0.293 ?mol/sec and the oxygen consumption as 10.06 ?mol/min. The other cobalt (II) phthalocyanine derived by chalcone with thiophene has given catalytic specifications such as turnover number TON as 15.9, initial reaction rate as 0.213 ?mol/sec and the oxygen consumption as 9.88 ?mol/min. So chalcone derived phthalocyanines can be used as catalyst is oxidation of mercaptan by air.Öğe Niğde-Ulukışla bitümlü şistinin kesikli bir reaktörde katalitik ve katalitik olmayan koşullarda sıvılaştırılması(2007) Karaca, Hüseyin; Akın, Serhat; Kartal, Esen Özlem; Hasçakır, Berna[Abstract Not Available]