Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene
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Dosyalar
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Öz: Cobalt (II) phthalocyanines carrying on the four of the peripheral positions furan and thiophene as chalcones were sythesized. THF is used to investigate the catalytic oxidation of 2-mercaptoethanol. The synthesized phthalocyanines show catalytic activity on the oxidation of 2-mercaptoethanol. Cobalt (II) phthalocyanine derived by chalcone with furan has given catalytic specifications such as turnover number TON as 16.6, initial reaction rate as 0.293 ?mol/sec and the oxygen consumption as 10.06 ?mol/min. The other cobalt (II) phthalocyanine derived by chalcone with thiophene has given catalytic specifications such as turnover number TON as 15.9, initial reaction rate as 0.213 ?mol/sec and the oxygen consumption as 9.88 ?mol/min. So chalcone derived phthalocyanines can be used as catalyst is oxidation of mercaptan by air.
Açıklama
Yıl: 2018Cilt: 22Sayı: 6ISSN: 1301-4048 / 2147-835XSayfa Aralığı: 1699 - 1703Metin Dili:İngilizce
Anahtar Kelimeler
Kaynak
Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
WoS Q Değeri
Scopus Q Değeri
Cilt
22
Sayı
6
Künye
KARACA H (2018). Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(6), 1699 - 1703. Doi: 10.16984/saufenbilder.407781
