Electrical and photoelectrical characterization of organic-inorganic heterostructures based on Ru-N-heterocyclic carbene complexes

dc.authoridTOMBAK, Ahmet/0000-0002-9997-1653
dc.authoridOcak, Yusuf Selim/0000-0001-8754-1720
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridbinbay, nil ertekin/0000-0002-2488-0378
dc.authoridBaysal, Akin/0000-0001-7294-6792
dc.authoridAydemir, Murat/0000-0002-4238-5012
dc.authorwosidTOMBAK, Ahmet/AAC-4985-2022
dc.authorwosidDurap, Feyyaz/U-1707-2017
dc.authorwosidOcak, Yusuf Selim/AAH-7230-2019
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidbinbay, nil ertekin/C-8039-2019
dc.authorwosidBaysal, Akin/I-6378-2018
dc.contributor.authorYasar, Sedat
dc.contributor.authorCekirdek, Suzan
dc.contributor.authorBinbay, Nil Ertekin
dc.contributor.authorTombak, Ahmet
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorArslan, Nevin
dc.contributor.authorBaysal, Akin
dc.date.accessioned2024-08-04T20:44:07Z
dc.date.available2024-08-04T20:44:07Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstract1,3-Bis(2-morpholinethyl)benzimidazoliumtrichlorido(eta(6)-p-cymene)-ruthenate(11), 2, was synthesized and characterized by NMR spectroscopy and micro analysis. The organic -inorganic heterojunctions were fabricated by using n-type Si wafer and a series of Ru-N-heterocyclic carbene complexes, 3-5, bearing sterically hindered aryl groups were documented for the first time. The thin films of the complexes are deposited on n-Si substrates using spin coating. Current-voltage (I-V) measurements of the devices in dark and illuminated environments were analyzed to determine electrical parameters of devices. Furthermore, the photoelectrical properties of the structures were investigated examined using I-V measurements under a solar simulator. Complexes 3 and 5 showed very low series resistance resulting in high rectification ratios which are promising results for the future electronic and photoelectronic applications. (C) 2017 Published by Elsevier GmbH.en_US
dc.description.sponsorshipTurkish Academy of Sciences; Dicle University [FEN.16.010, DUBAP FEN.17.023]en_US
dc.description.sponsorshipPartial supports of this work by Turkish Academy of Sciences and Dicle University (Project numbers: FEN.16.010 (NMR) and DUBAP FEN.17.023) is gratefully acknowledged. S. Yapr, S. cekirdek and N.E. Binbay synthesized compounds 1, 3 and 4 according to the references given in the manuscript, while A. Baysal, F. Durap and N. Arslan synthesized original compound 2. Finally, A. Tombak, Y.S. Ocak and M. Aydemir tested electrical and photoelectrical properties of the compounds.en_US
dc.identifier.doi10.1016/j.ijleo.2017.11.204
dc.identifier.endpage521en_US
dc.identifier.issn0030-4026
dc.identifier.scopus2-s2.0-85035770276en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage514en_US
dc.identifier.urihttps://doi.org/10.1016/j.ijleo.2017.11.204
dc.identifier.urihttps://hdl.handle.net/11616/98045
dc.identifier.volume156en_US
dc.identifier.wosWOS:000424311500066en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Gmbhen_US
dc.relation.ispartofOptiken_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectRuthenium complexen_US
dc.subjectHeterojunctionsen_US
dc.subjectElectrical propertiesen_US
dc.titleElectrical and photoelectrical characterization of organic-inorganic heterostructures based on Ru-N-heterocyclic carbene complexesen_US
dc.typeArticleen_US

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