Novel N-Alkylbenzimidazole-Ruthenium (II) complexes: Synthesis and catalytic activity of N-alkylating reaction under solvent-free medium

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dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidŞAHİN, Neslihan/F-6402-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorSahin, Neslihan
dc.contributor.authorOzdemir, Namik
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:45:37Z
dc.date.available2024-08-04T20:45:37Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this article, direct N-alkylation reactions of amines with alcohols derivatives have been investigated. For this purpose, a new series ruthenium (II) complexes bearing N-coordinated benzimidazole complexes with have been synthesized and fully characterized by elemental analysis, FT-IR, H-1 NMR and, C-13 NMR spectroscopies. Additionally, the structures of the complexes 2b and 2c have been confirmed by X-ray crystallography. Although the N-alkylating reaction is usually performed in toluene, the catalytic study of complexes 2a-d has carried out no additional solvent and alcohol acted both as solvent and reactant of alkylating by using a little excess of alcohols. Surprisingly, conversion and selectivity of amine product for alkylation reaction have been seen high in medium solvent-free relative to in toluene.en_US
dc.identifier.doi10.1002/aoc.4704
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85058966222en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.4704
dc.identifier.urihttps://hdl.handle.net/11616/98586
dc.identifier.volume33en_US
dc.identifier.wosWOS:000456252400003en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcatalysisen_US
dc.subjectcrystal structureen_US
dc.subjectN-alkylationen_US
dc.subjectN-coordinated benzimidazoleen_US
dc.subjectrutheniumen_US
dc.titleNovel N-Alkylbenzimidazole-Ruthenium (II) complexes: Synthesis and catalytic activity of N-alkylating reaction under solvent-free mediumen_US
dc.typeArticleen_US

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