Desulfurization of fuel by leaching using H2O2 and H2SO4

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dc.authoridKaraca, Huseyin/0000-0002-0543-8947
dc.authorwosidKaraca, Huseyin/ABG-8103-2020
dc.contributor.authorKaraca, H
dc.contributor.authorYildiz, Z
dc.date.accessioned2024-08-04T20:13:51Z
dc.date.available2024-08-04T20:13:51Z
dc.date.issued2005
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this research, different concentrations of H2O2 and H2SO4 solutions were used in order to remove the sulfur from high sulfur contented No. 6 fuel oil. In desulphurization experiments, reaction temperature, reaction time, and the concentration of H2O2 and H2SO4 were varied in a range of 20-50 degrees C, 30-150 min, 5-35%, and 0.05-2.00 N, respectively. The ratio of reagent/fuel oil was taken as 10/1 and the stirring speed as 1,000 rpm. According to the results obtained, considering the desulphurization and the organic structure of the fuel, the most appropriate method was found as the H2O2 leaching method. It was barely determined that the highest desulphurization was achieved by H2O2/0.1N H2SO4 leaching method. The optimum process parameters for H2O2 leaching method were found as a concentration of 15%, reaction temperature of 30 degrees C, and reaction time of 60 min; and for H2SO4 leaching method were found as concentration of 0.1 N, reaction temperature of 30 degrees C, and reaction time of 150 min. It was observed that by increasing the reaction temperature, reaction time, and reagent concentration, the carbon and hydrogen contents of the fuel decreased considerably and on the contrary the oxygen content increased very rapidly. A partial decrease of nitrogen content was also observed.en_US
dc.identifier.doi10.1081/LFT-200028294
dc.identifier.endpage298en_US
dc.identifier.issn1091-6466
dc.identifier.issue3-4en_US
dc.identifier.scopus2-s2.0-17444414186en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage285en_US
dc.identifier.urihttps://doi.org/10.1081/LFT-200028294
dc.identifier.urihttps://hdl.handle.net/11616/93891
dc.identifier.volume23en_US
dc.identifier.wosWOS:000228524700007en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofPetroleum Science and Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectfuel oilen_US
dc.subjectprocesses parametersen_US
dc.subjectdesulphurizationen_US
dc.subjectdesulphurization methodsen_US
dc.subjectelemental analysisen_US
dc.titleDesulfurization of fuel by leaching using H2O2 and H2SO4en_US
dc.typeArticleen_US

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