Experimental characterization and theoretical investigation of Ce/Yb co-doped hydroxyapatites

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dc.authoridBulut, Niyazi/0000-0003-2863-7700
dc.authoridKebiroglu, Hanifi/0000-0002-6764-3364
dc.authoridAteş, Burhan/0000-0001-6080-229X
dc.authoridDorozhkin, Sergey V./0000-0002-8439-9527
dc.authoridKaygili, Omer/0000-0002-2321-1455
dc.authoridAtes, Tankut/0000-0002-4519-2953
dc.authoridErcan, Filiz/0000-0002-3533-0726
dc.authorwosidBulut, Niyazi/E-2862-2010
dc.authorwosidKebiroglu, Hanifi/AAW-7084-2020
dc.authorwosidAteş, Burhan/AAA-3730-2021
dc.authorwosidDorozhkin, Sergey V./H-1808-2011
dc.authorwosidKaygili, Omer/A-4801-2017
dc.authorwosidAtes, Tankut/AAK-2168-2020
dc.contributor.authorAcar, Serdar
dc.contributor.authorKaygili, Omer
dc.contributor.authorAtes, Tankut
dc.contributor.authorDorozhkin, Sergey, V
dc.contributor.authorBulut, Niyazi
dc.contributor.authorAtes, Burhan
dc.contributor.authorKoytepe, Suleyman
dc.date.accessioned2024-08-04T20:50:51Z
dc.date.available2024-08-04T20:50:51Z
dc.date.issued2022
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn the present study, the effects of variable amounts of Yb addition on the structural, thermal, and in vitro biocompatibility properties of Ce-doped hydroxyapatite (HAp) samples synthesized via the wet chemical method were investigated. Besides, the prepared formulations were also modeled for making the theoretical investigations. The single-phase compositions were detected for all samples, and no formation of additional phases was observed. Doping with Yb was observed to produce some variations in the lattice parameters, unit cell volume, lattice strain, and lattice stress. While a decreasing trend in the crystallite size and crystallization percent with increasing Yb content was found, a gradual increase in the anisotropic energy density was observed. All samples were found to be thermally stable from room temperature to 1000 degrees C with negligible mass losses during heating. No significant morphological changes were caused by the addition of Yb. For all samples, the numerical values of (Ca + Ce + Yb)/P molar ratio were found to be close to that for stoichiometric HAp (1.67). It was observed that the increased Yb additive caused a decrease in cell viability values. A continuous decrease in the bandgap energy with the increasing amounts of Yb added to the Ce-based HAp structure was observed from the theoretical investigations. A sharp decrease in the cell viability of the Ce-based HAp was observed with the addition of Yb.en_US
dc.description.sponsorshipManagement Unit of Scientific Research Projects of Firat University (FuBAP) [FF.19.22]en_US
dc.description.sponsorshipThis work was supported by the Management Unit of Scientific Research Projects of Firat University (FuBAP) (Project Number: FF.19.22) .en_US
dc.identifier.doi10.1016/j.matchemphys.2021.125444
dc.identifier.issn0254-0584
dc.identifier.issn1879-3312
dc.identifier.scopus2-s2.0-85119173726en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2021.125444
dc.identifier.urihttps://hdl.handle.net/11616/100308
dc.identifier.volume276en_US
dc.identifier.wosWOS:000744256500002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofMaterials Chemistry and Physicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectIon-substituted hydroxyapatiteen_US
dc.subjectWet chemical methoden_US
dc.subjectCeen_US
dc.subjectYben_US
dc.subjectCell viability testen_US
dc.titleExperimental characterization and theoretical investigation of Ce/Yb co-doped hydroxyapatitesen_US
dc.typeArticleen_US

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