Investigation of hybrid-capacitor properties of ruthenium complexes

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridALTUNDAĞ, Sebahat/0000-0002-4777-8376
dc.authoridALTIN, Serdar/0000-0002-4590-907X
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authoridOz, Erdinc/0000-0003-4321-8264
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidALTUNDAĞ, Sebahat/AAB-4167-2021
dc.authorwosidbayri, ali/AAA-5966-2021
dc.authorwosidALTIN, Serdar/H-4880-2014
dc.authorwosidOz, Erdinc/GXW-0937-2022
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorAltin, Serdar
dc.contributor.authorOz, Erdinc
dc.contributor.authorAltundag, Sebahat
dc.contributor.authorBayri, Ali
dc.contributor.authorRoisnel, Thierty
dc.contributor.authorDorcet, Vincent
dc.contributor.authorBruneau, Christian
dc.date.accessioned2024-08-04T20:46:05Z
dc.date.available2024-08-04T20:46:05Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractRu complexes were successfully produced, and their structural properties were investigated using FTIR, Raman, and single crystal XRD patterns. The HOMO, LUMO, Eg, and electronic surface potential (ESP) values of the molecules were calculated by a Gaussian program. The complexes were used for producing hybrid capacitor cells as electrode materials. According to electrochemical analysis, complex 2 showed the best CV graph between -1 V and +1 V and had the highest current value and hysteresis area when compared with the other complexes. The performance analysis and the capacity fade of the cells were investigated. The first capacity values of the complexes were 57.5, 22.1, 16.9, and 0.0021 F/g for complexes 1, 2, 3, and 4, respectively. The capacitive mechanism of the cells as relates to molecular interactions was also investigated. We suggested that the ESP values of the molecules were directly related to the capacitive performance of the cells. In addition to this, the best cycling performance was obtained for complex 2, which has the lowest Eg value among the complexes. We speculate that the charged regions on the complex materials have a crucial role in the increasing the capacitance of the cells.en_US
dc.description.sponsorshipInonu University [BAP-2016/93]; Inonu University Research Council [FCD-2017-730]en_US
dc.description.sponsorshipInonu University, Grant/Award Number: BAP-2016/93; Inonu University Research Council, Grant/Award Number: FCD-2017-730en_US
dc.identifier.doi10.1002/er.4690
dc.identifier.endpage6851en_US
dc.identifier.issn0363-907X
dc.identifier.issn1099-114X
dc.identifier.issue13en_US
dc.identifier.scopus2-s2.0-85069893366en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage6840en_US
dc.identifier.urihttps://doi.org/10.1002/er.4690
dc.identifier.urihttps://hdl.handle.net/11616/98888
dc.identifier.volume43en_US
dc.identifier.wosWOS:000476280000001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-Hindawien_US
dc.relation.ispartofInternational Journal of Energy Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectelectrochemical capacitoren_US
dc.subjecthybrid capacitoren_US
dc.subjectRu complexen_US
dc.titleInvestigation of hybrid-capacitor properties of ruthenium complexesen_US
dc.typeArticleen_US

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