Synthesis of silica-supported rhodium carbene complex as efficient catalyst for the addition of phenylboronic acid to aldehydes

Küçük Resim Yok

Tarih

2005

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Wiley

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Silica-supported catalytically active functional materials, such as the rhodium(l) carbene complex with 1-(triethoxysilylpropyl)-3-(2,4,6-trimethylbenzyl)imidazolidine-2-ylidine (L), were prepared using the sol-gel method. The complex (1; COD = 1,5-cyclooctadiene) RhCl(COD)[1-(triethoxysilylpropyl)3-(2,4,6-trimethylbenzyl)imidazolidin-2-ylidine] was characterized by conventional spectroscopic methods and elemental analyses and the silica-supported functional material RhCl(COD)(L) were tested for the catalytic addition of phenylboronic acid to aldehydes. Copyright (c) 2005 John Wiley & Sons, Ltd.

Açıklama

Anahtar Kelimeler

silica-supported catalysis, N-heterocyclic carbene, imidazolidinylidine

Kaynak

Applied Organometallic Chemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

19

Sayı

5

Künye