Synthesis of silica-supported rhodium carbene complex as efficient catalyst for the addition of phenylboronic acid to aldehydes
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Silica-supported catalytically active functional materials, such as the rhodium(l) carbene complex with 1-(triethoxysilylpropyl)-3-(2,4,6-trimethylbenzyl)imidazolidine-2-ylidine (L), were prepared using the sol-gel method. The complex (1; COD = 1,5-cyclooctadiene) RhCl(COD)[1-(triethoxysilylpropyl)3-(2,4,6-trimethylbenzyl)imidazolidin-2-ylidine] was characterized by conventional spectroscopic methods and elemental analyses and the silica-supported functional material RhCl(COD)(L) were tested for the catalytic addition of phenylboronic acid to aldehydes. Copyright (c) 2005 John Wiley & Sons, Ltd.
Açıklama
Anahtar Kelimeler
silica-supported catalysis, N-heterocyclic carbene, imidazolidinylidine
Kaynak
Applied Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
19
Sayı
5