Arylation of heterocyclic compounds by benzimidazole-based N-heterocyclic carbene-palladium(II) complexes

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridKARABIYIK, HANDE/0000-0001-6180-2080;
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKARABIYIK, HANDE/O-9745-2019
dc.authorwosidŞAHİN, Neslihan/F-6402-2019
dc.contributor.authorSahin, Neslihan
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorKarabiyik, Hande
dc.contributor.authorKarabiyik, Hasan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:47:02Z
dc.date.available2024-08-04T20:47:02Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSpecific C-H bond can be activated for arylation using aryl halide without the aid of directing the group in the case of electron-rich heteroarenes. The ability to readily generate halo substituted arylated heteroarenes is important in organic chemistry since these species are important building blocks for biochemists. In this manuscript, we report the synthesis of PEPPSI type-novel benzimidazole-based N-heterocyclic carbene-palladium(II) complexes (2a-e). All of the new compounds were fully characterized by H-1, C-13{H-1} NMR and FT-IR spectra. The structures of 2c, 2d, and 2e were determined by X-ray crystallography and the prepared complexes (2a-e) were investigated as catalysts for the direct arylation of 2-n-propylthiazole, 4,5-dimethylthiazole and 2-acetylthiophene with various aryl bromides. High catalytic activity for arylation was seen reaction using only 0.5 mol% catalyst for 1 h. (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research of Turkey (TUBITAK-BIDEB) the National Research Fellowship Programme; Dokuz Eylul University [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors thank the Scientific and Technological Research of Turkey (TUBITAK-BIDEB) the National Research Fellowship Programme for grants to N. S. Hande K. and Hasan K. acknowledge Dokuz Eylul University for the use of the Agilent Xcalibur Eos diffractometer (purchased under University Research grant No. 2010.KB.FEN.13).en_US
dc.identifier.doi10.1016/j.jorganchem.2019.121076
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85076631389en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2019.121076
dc.identifier.urihttps://hdl.handle.net/11616/99102
dc.identifier.volume907en_US
dc.identifier.wosWOS:000506406600001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectBenzimidazoleen_US
dc.subjectPEPPSIen_US
dc.subjectDirect arylationen_US
dc.subjectThiophenesen_US
dc.subjectThiazolesen_US
dc.titleArylation of heterocyclic compounds by benzimidazole-based N-heterocyclic carbene-palladium(II) complexesen_US
dc.typeArticleen_US

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