In situ generated rhodium-based catalyst for addition of phenylboronic acid to aldehydes

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidYiğit, Mehmet/HLQ-7874-2023
dc.contributor.authorYigit, M
dc.contributor.authorÖzdemir, I
dc.contributor.authorÇetinkaya, E
dc.contributor.authorÇetinkaya, B
dc.date.accessioned2024-08-04T20:15:05Z
dc.date.available2024-08-04T20:15:05Z
dc.date.issued2005
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew 1,3-dialkylperhydrobenzimidazolinium and 1,3-dialkylimidazolinium salts (2,4) as NHC precursors have been synthesized and characterized. These salts in combination with [RhCl(COD)](2) provided active catalysts for the addition of phenylboronic acid to aldehydes under mild conditions. The in situ prepared three-component system [RhCl(COD)](2)/imidazolinium salts (2,4) and KOBu' catalyse the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. (c) 2005 Wiley Periodicals, Inc.en_US
dc.identifier.doi10.1002/hc.20132
dc.identifier.endpage465en_US
dc.identifier.issn1042-7163
dc.identifier.issn1098-1071
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-27744585125en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage461en_US
dc.identifier.urihttps://doi.org/10.1002/hc.20132
dc.identifier.urihttps://hdl.handle.net/11616/94167
dc.identifier.volume16en_US
dc.identifier.wosWOS:000231987700001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-Hindawien_US
dc.relation.ispartofHeteroatom Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransition-Metal-Complexesen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectEfficient Catalystsen_US
dc.subjectAryl Chloridesen_US
dc.subjectPalladiumen_US
dc.subjectMetathesisen_US
dc.subjectHydroformylationen_US
dc.subjectDerivativesen_US
dc.subjectAminationen_US
dc.subjectLigandsen_US
dc.titleIn situ generated rhodium-based catalyst for addition of phenylboronic acid to aldehydesen_US
dc.typeArticleen_US

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