Novel 2-hydroxyethyl substituted N-coordinate-Pd(II)(NHC) and bis(NHC)Pd(II) complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction

Küçük Resim Yok

Tarih

2019

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Indian Acad Sciences

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

The direct arylation reaction has attracted attention in recent years especially because of its environment-friendly properties. In this study, we researched the synthesis of 2-hydroxyethyl substituted bis(NHC)Pd(II) complexes and also the synthesis of N-coordinate-Pd(II)(NHC) complexes containing N-bound benzimidazolium from palladium acetate ([Pd(CH3COO)(2)]) with 1,3-disubstituted benzimidazolium halides in DMSO. All the complexes have been characterized by using H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. The molecular and crystal structure of one of the complexes is confirmed by using single-crystal X-ray diffraction. These complexes have been examined as the catalyst in the direct arylation reaction with 2-n-butylfuran and 2-n-butylthiophene and have demonstrated excellent activity in this reaction.

Açıklama

Anahtar Kelimeler

Bis(NHC)Pd(II) complex, butylfuran, butylthiophene, direct arylation, N-coordinate-Pd(II)(NHC) complexes, N-heterocyclic carbene

Kaynak

Journal of Chemical Sciences

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

131

Sayı

8

Künye