Antioxidant activities of the new tetrasubstituted metal-free, Zn(II) and Co(II) monophthalocyanines

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dc.authoridŞAHİN-BÖLÜKBAŞI, Serap/0000-0003-1057-2558
dc.authoridYabas, Ebru/0000-0001-7163-3057
dc.authorwosidŞAHİN-BÖLÜKBAŞI, Serap/ABJ-7836-2022
dc.authorwosidYABAŞ, EBRU/AAH-4372-2019
dc.authorwosidSÜLÜ, Mustafa/ABH-5282-2020
dc.contributor.authorSoylemez, Nazli
dc.contributor.authorYabas, Ebru
dc.contributor.authorBolukbasi, Serap Sahin
dc.contributor.authorSulu, Mustafa
dc.date.accessioned2024-08-04T20:44:24Z
dc.date.available2024-08-04T20:44:24Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstract4-[(4'-(Tert-butyl) phenoxy) phenoxy] phthalonitrile 1 has been prepared by the reaction of 4-(4-nitrophenoxy) phthalonitrile with 4-tertiarylbutylphenole. 4-((4'-tert-butyl) phenoxy) phenoxy tetrasubstituted metal-free 2, zinc(II) 3 and cobalt(II) 4 phthalocyanines have been prepared by tetramerization of compound 1. The synthesized phthalocyanines showed high solubility in common organic solvents such as CHCl3. All compounds were characterized by elemental analysis and H-1-NMR, C-13-NMR, UV-vis, IR spectra. Aggregation behaviors of these compounds have been investigated in different solvents (CHCl3, THF, DMF and DMSO) and different concentrations in CHCl3. The in vitro antioxidant activities of phthalocyanine compounds 2, 3 and 4 were evaluated in a series of assays involving DPPH radicals, hydroxyl radicals, superoxide radicals, singlet oxygen and hydrogen peroxide. Antioxidant activity of compound 2 was found to be higher than that of compounds 3 and 4.en_US
dc.identifier.doi10.1142/S1088424618500190
dc.identifier.endpage242en_US
dc.identifier.issn1088-4246
dc.identifier.issn1099-1409
dc.identifier.issue1-3en_US
dc.identifier.scopus2-s2.0-85044249757en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage233en_US
dc.identifier.urihttps://doi.org/10.1142/S1088424618500190
dc.identifier.urihttps://hdl.handle.net/11616/98205
dc.identifier.volume22en_US
dc.identifier.wosWOS:000427932100025en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWorld Sci Publ Co Incen_US
dc.relation.ispartofJournal of Porphyrins and Phthalocyaninesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectsynthesisen_US
dc.subjectaggregationen_US
dc.subjectantioxidant activityen_US
dc.titleAntioxidant activities of the new tetrasubstituted metal-free, Zn(II) and Co(II) monophthalocyaninesen_US
dc.typeArticleen_US

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