RHODIUM(I) N-HETEROCYCLIC CARBENE COMPLEXES AS CATALYSTS FOR THE ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENE

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dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorGok, Yetkin
dc.contributor.authorYigit, Beyhan
dc.contributor.authorCelikal, Ozlem Ozeroglu
dc.contributor.authorYigit, Murat
dc.date.accessioned2024-08-04T20:50:14Z
dc.date.available2024-08-04T20:50:14Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of new rhodium(I) complexes with benzimidazole based N-heterocyclic carbene (NHC) ligand were synthesized by reactions of benzimidazolium salts with [Rh(OMe)COD](2). The characterization of rhodium(I) complexes with the general formula [RhCl(NHC)(eta(4)-1,5-cyclooctadiene)] was done by physicochemical and spectroscopic methods. All the synthesized complexes were tested as catalysts in the intermolecular hydroamination reactions between styrene with aromatic amines in ionic liquid. All of these complexes tested here are catalytically active for the intermolecular hydroamination of styrene with aromatic amines in ionic liquid. The anti-Markovnikov addition products were obtained selectively by using 1 mol% of the rhodium complex.en_US
dc.description.sponsorshipTurkish Research Council (TUBITAK) [107T419]en_US
dc.description.sponsorshipWe thank to Turkish Research Council (TUBITAK) (Project Number: 107T419) for financial support of this work.en_US
dc.identifier.doi10.3987/COM-21-14430
dc.identifier.endpage953en_US
dc.identifier.issn0385-5414
dc.identifier.issn1881-0942
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85105822456en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage941en_US
dc.identifier.urihttps://doi.org/10.3987/COM-21-14430
dc.identifier.urihttps://hdl.handle.net/11616/99924
dc.identifier.volume102en_US
dc.identifier.wosWOS:000719566400010en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofHeterocyclesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectIntermolecular Hydroaminationen_US
dc.subjectIntramolecular Hydroaminationen_US
dc.subjectUnactivated Alkenesen_US
dc.subjectAlkaline-Earthen_US
dc.subjectAsymmetric Hydroaminationen_US
dc.subjectHydroarylation Reactionsen_US
dc.subjectAlkyne Hydroaminationen_US
dc.subjectIridium(I) Complexesen_US
dc.subjectLigands Synthesisen_US
dc.subjectTerminal Alkynesen_US
dc.titleRHODIUM(I) N-HETEROCYCLIC CARBENE COMPLEXES AS CATALYSTS FOR THE ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENEen_US
dc.typeArticleen_US

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