Synthesis, structural characterization and biological activities of metal(II) complexes with Schiff bases derived from 5-bromosalicylaldehyde: Ru(II) complexes transfer hydrogenation

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dc.authoridTuran, Nevin/0000-0001-6740-6812
dc.authoridBULDURUN, Kenan/0000-0002-2462-7006
dc.authorwosidTuran, Nevin/AAB-8583-2019
dc.authorwosidBULDURUN, Kenan/AAD-5162-2019
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorTuran, Nevin
dc.contributor.authorSavci, Ahmet
dc.contributor.authorColak, Naki
dc.date.accessioned2024-08-04T20:44:38Z
dc.date.available2024-08-04T20:44:38Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, two novel Schiff base ligands (L-1 and L-2) derived from condensation of methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate and methyl 2-amino-6-phenyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate, both starting matter with 5-bromo-salicylaldehyde, and their Zn(II) and Ni(II) metal complexes have been prepared using a molar ratio of ligand:metal as 1:1 except the Ru(II) complexes 1:0.5. The structures of the obtained ligands and their metal complexes were characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, UV-vis, thermal analysis methods, mass spectrometry, and magnetic susceptibility measurements. Antioxidant and antiradical activity of Schiff base ligands and their metal complexes were been evaluated in vitro tests. Antioxidant activities of metal complexes generally were more effectives than free Schiff bases. 1c and 2c were used as catalysts for the transfer hydrogenation (TH) of ketones. 1c, 2c complexes were found to be efficient catalyst for transfer hydrogenation reactions. (C) 2018 King Saud University. Production and hosting by Elsevier B.V.en_US
dc.identifier.doi10.1016/j.jscs.2018.06.002
dc.identifier.endpage214en_US
dc.identifier.issn1319-6103
dc.identifier.issn2212-4640
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85049732364en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage205en_US
dc.identifier.urihttps://doi.org/10.1016/j.jscs.2018.06.002
dc.identifier.urihttps://hdl.handle.net/11616/98375
dc.identifier.volume23en_US
dc.identifier.wosWOS:000456445700010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Saudi Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAntioxidant activityen_US
dc.subjectAntiradical activityen_US
dc.subjectTransition metalsen_US
dc.subjectCarboxylate liganden_US
dc.subjectTransfer hydrogenationen_US
dc.titleSynthesis, structural characterization and biological activities of metal(II) complexes with Schiff bases derived from 5-bromosalicylaldehyde: Ru(II) complexes transfer hydrogenationen_US
dc.typeArticleen_US

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