Carbon-carbon bond formation catalyzed by PEPPSI Pd-NHC
dc.authorid | Akkoc, Senem/0000-0002-1260-9425 | |
dc.authorid | Kayser, Veysel/0000-0003-1310-9534 | |
dc.authorwosid | Kayser, Veysel/HKN-5249-2023 | |
dc.authorwosid | Gök, Yetkin/AAA-5669-2021 | |
dc.authorwosid | İLHAN, İLHAN ÖZER/AAN-1469-2021 | |
dc.authorwosid | Akkoç, Senem/AAN-1478-2021 | |
dc.contributor.author | Akkoc, Senem | |
dc.contributor.author | Ilhan, Ilhan Ozer | |
dc.contributor.author | Gok, Yetkin | |
dc.contributor.author | Kayser, Veysel | |
dc.date.accessioned | 2024-08-04T20:43:00Z | |
dc.date.available | 2024-08-04T20:43:00Z | |
dc.date.issued | 2017 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | Five new palladium complexes were efficiently synthesized from the reaction of benzimidazolium salts, potassium carbonate (K2CO3) and palladium chloride (PdCl2) in pyridine (for 3-5) or 3-chloropyridine (for 6 and 7). The synthesized complexes were characterized and tested in Suzuki-Miyaura cross-coupling reaction as catalysts. In the presence of catalysts 3-7, biaryl products were obtained in moderate yields when phenylboronic acid was used as boronic acid derivative. However, the coupling of thianaphthene-2-boronic acid with 1-chloro-4-nitrobenzene generated low yields although a longer period of time was used in comparison to the coupling of phenylboronic acid with aryl chlorides. (C) 2017 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Erciyes University Research Fund [FBA-2013-4307] | en_US |
dc.description.sponsorship | This work was financially supported by Erciyes University Research Fund (FBA-2013-4307). | en_US |
dc.identifier.doi | 10.1016/j.ica.2017.01.025 | |
dc.identifier.endpage | 56 | en_US |
dc.identifier.issn | 0020-1693 | |
dc.identifier.issn | 1873-3255 | |
dc.identifier.scopus | 2-s2.0-85013439222 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 52 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2017.01.025 | |
dc.identifier.uri | https://hdl.handle.net/11616/97700 | |
dc.identifier.volume | 461 | en_US |
dc.identifier.wos | WOS:000399712200008 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Science Sa | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | N-Heterocyclic carbene | en_US |
dc.subject | PEPPSI complex | en_US |
dc.subject | Palladium | en_US |
dc.subject | Suzuki-Miyaura cross-coupling reaction | en_US |
dc.subject | Catalyst | en_US |
dc.title | Carbon-carbon bond formation catalyzed by PEPPSI Pd-NHC | en_US |
dc.type | Article | en_US |