Synthesis and catalytic applications of palladium N-heterocyclic carbene complexes as efficient pre-catalysts for Suzuki-Miyaura and Sonogashira coupling reactions

Basit Öğe Kaydı
dc.authoridBen hamadi, Naoufel/0000-0002-2410-5275
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidBen hamadi, Naoufel/ABA-5053-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorBoubakri, L.
dc.contributor.authorYasar, S.
dc.contributor.authorDorcet, V.
dc.contributor.authorRoisnel, T.
dc.contributor.authorBruneau, C.
dc.contributor.authorHamdi, N.
dc.contributor.authorOzdemir, I.
dc.date.accessioned2024-08-04T20:43:14Z
dc.date.available2024-08-04T20:43:14Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA new palladium complex series with N-heterocyclic carbene (NHC), pyridine and phosphine ligands, PdCl2(L)NHC (2a-c)(L = NHC), PdCl2(L-1)NHC(3a-c)(L-1 = pyridine), PdCl2(L-2)NHC(4a-c)(L-2 = triphenyl-phosphine) was synthesised and fully characterized. The catalytic activities of these complexes were screened for the Sonogashira and Suzuki-Miyaura reactions between arylhalides and phenylacetylene, and phenylboronic acid, respectively. The results pointed out that the carbene/phosphine complexes 4a-c exhibited excellent catalytic activities as compared to 2a-c, 3a-c, and the well-known systems for the palladium-catalysed Sonogashira reaction. The reactivity of 4a-c in these preliminary Sonogashira coupling tests seems to be higher than that of previously reported catalytic systems based on Pd(NHC) moieties. These new palladium NHC complexes are among the first reported palladium catalysts that are efficient for catalysing the Sonogashira reaction from arylchloride substrates.en_US
dc.description.sponsorshipInonu University Research Fund [BAP: 2016-195]en_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (BAP: 2016-195).en_US
dc.identifier.doi10.1039/c7nj00488e
dc.identifier.endpage5113en_US
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85021803163en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5105en_US
dc.identifier.urihttps://doi.org/10.1039/c7nj00488e
dc.identifier.urihttps://hdl.handle.net/11616/97878
dc.identifier.volume41en_US
dc.identifier.wosWOS:000403340100056en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofNew Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAryl Chloridesen_US
dc.subjectRoom-Temperatureen_US
dc.subjectCopper-Freeen_US
dc.subjectAmine-Freeen_US
dc.subjectDehydrogenative Silylationen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectPhospha-Palladacyclesen_US
dc.subjectCross-Couplingsen_US
dc.subjectNhcen_US
dc.subjectLigandsen_US
dc.titleSynthesis and catalytic applications of palladium N-heterocyclic carbene complexes as efficient pre-catalysts for Suzuki-Miyaura and Sonogashira coupling reactionsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu