Synthesis, Characterization and Catalytic Activity of New N-Heterocyclic Bis(carbene)ruthenium Complexes

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidTOUPET, Loic/N-7043-2014
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorToupet, Loic
dc.contributor.authorBruneau, Christian
dc.contributor.authorDixneuf, Pierre H.
dc.date.accessioned2024-08-04T20:31:15Z
dc.date.available2024-08-04T20:31:15Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reaction of RuCl2(PPh3)(3) with tBuOK-deprotonated ortho-xylyl-bis(N-imidazolinium) salts 1a-d yields RuCl2(PPh3)[bis(imidazolidin-2-ylidene)] complexes (2a-d). Under similar conditions, [RuCl2(p-cymene)](2) leads to the ruthenium complex 3 containing a tridentate eta(6)-arene-dicarbene ligand. All synthesized compounds were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of 2a, 2b and 3 were determined by X-ray crystallography. The catalytic activity of RuCl2(PPh3)[bis(imidazolidin-2-ylidene)] complexes 2a-b was evaluated in the direct arylation of 2-phenylpyridine with chlorobenzene derivatives. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK; CNRS (France) [TBAG-U/181 (106T716)]; Inonu University Research Fund (I.U. B.A.P: 2008/Gudumlu 3); European Commission (NoE IDECAT) [NMP3-CT-2005-011730]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK, CNRS (France) [TBAG-U/181 (106T716)] and the Inonu University Research Fund (I.U. B.A.P: 2008/Gudumlu 3). Thanks are due for the financial support provided by the European Commission (NoE IDECAT, NMP3-CT-2005-011730).en_US
dc.identifier.doi10.1002/ejic.200801189
dc.identifier.endpage1949en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issue13en_US
dc.identifier.scopus2-s2.0-66149173672en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1942en_US
dc.identifier.urihttps://doi.org/10.1002/ejic.200801189
dc.identifier.urihttps://hdl.handle.net/11616/94805
dc.identifier.wosWOS:000266191000030en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRutheniumen_US
dc.subjectCarbenesen_US
dc.subjectBis(imidazolinium) saltsen_US
dc.subjectN ligandsen_US
dc.subjectC-H activationen_US
dc.titleSynthesis, Characterization and Catalytic Activity of New N-Heterocyclic Bis(carbene)ruthenium Complexesen_US
dc.typeArticleen_US

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