Active ruthenium(II)-NHC complexes for alkylation of amines with alcohols using solvent-free conditions

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorYigit, Beyhan
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorYigit, Murat
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorArslan, Hakan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:56Z
dc.date.available2024-08-04T20:46:56Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of new ruthenium(II) complexes bearing N-heterocyclic carbene ligands with benzylic groups were prepared by transmetallation reactions between silver(I) N-heterocyclic carbene complexes and [RuCl2(P-cymene)](2). All of the obtained complexes were characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopy, and the molecular structure of compound 3c was also determined by X-ray crystallography. These ruthenium complexes were tested for the alkylation of aromatic amines with a wide range of primary alcohols under solvent-free conditions using the hydrogen borrowing strategy. All of the compounds tested here showed excellent catalytic activity for these reactions and N-monoalkylated products were obtained selectively using 2.5 mol% of the ruthenium complexes. (C) 2019 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipInonu University Research Fund [2016/76]en_US
dc.description.sponsorshipThis work was supported by the Inonu University Research Fund [Project No: 2016/76(Gud)].en_US
dc.identifier.doi10.1016/j.poly.2019.114234
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85075335237en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2019.114234
dc.identifier.urihttps://hdl.handle.net/11616/99060
dc.identifier.volume175en_US
dc.identifier.wosWOS:000504781100040en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRu-N-heterocyclic carbene complexen_US
dc.subjectX-ray crystallographyen_US
dc.subjectBorrowing hydrogenation reactionen_US
dc.subjectAlkylation of amineen_US
dc.titleActive ruthenium(II)-NHC complexes for alkylation of amines with alcohols using solvent-free conditionsen_US
dc.typeArticleen_US

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