Transfer hydrogenation of ketones in the presence of half sandwich ruthenium (II) complexes bearing imidazoline and benzimidazole ligand
Küçük Resim Yok
Tarih
2015
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Arkat Usa Inc
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
This article explores the possibility of using imidazoline and benzimidazole derivatives as interesting ligands due to the fact that they are structurally simple, readily available, inexpensive, and they allow easy introduction of various substituents into their structure. Therefore, N-substituted imidazoline and benzimidazole ligands and their new ruthenium complexes [RuCl2(eta(6)-p-cymene)(L)] (L = N-substituted imidazoline/benzimidazole) were synthesized and characterized. The catalytic performances of new complexes are investigated for the transfer hydrogenation of ketones. Furthermore, corresponding secondary alcohols were also obtained in good yields.
Açıklama
Anahtar Kelimeler
Azole ligands, ruthenium, transfer hydrogenation, ketones
Kaynak
Arkivoc
WoS Q Değeri
Q3
Scopus Q Değeri
Q4
