HYDROGENATION OF ACETOPHENONE AND ITS DERIVATIVES WITH 2-PROPANOL USING AMINOMETHYLPHOSPHINE-RUTHENIUM CATALYSIS

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridKeleş, Mustafa/0000-0003-2669-1818;
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKeleş, Mustafa/IYS-2882-2023
dc.authorwosidserindag, osman/G-3102-2012
dc.authorwosidKeleş, Mustafa/AAG-4664-2019
dc.contributor.authorKeles, Mustafa
dc.contributor.authorKeles, Tugba
dc.contributor.authorSerindag, Osman
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:32:15Z
dc.date.available2024-08-04T20:32:15Z
dc.date.issued2010
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reaction of 3'-aminopropyltriethoxysilane with the phosphonium salt ([Ph2P(CH2OH)(2)]Cl) gives an aminomethylphosphine-type ligand ((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2)). Reaction of the ligand ((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2)) with silica gives silica supported aminomethylphosphine ligand (SiO2)-O-Si(CH2)(3)N(CH2PPh2)(2)). The ligands were refluxed with [RuCl2(p-cymene)](2) in toluene to give [RuCl2((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2))] and silica-supported SiO2)-O-[RuCl2((Si(CH2)(3)N(CH2PPh2)(2))(2)] complex, respectively. The catalytic studies show that the complexes [RuCl2((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2))] and SiO2)-O-[RuCl2((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2))(2)] are very active catalysts for the transfer hydrogenation of acetophenone by 2-propanol in basic media. The best yield was observed in hydrogenation of m-methoxy acetophenone (95%) with catalyst [RuCl2((CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2))].en_US
dc.description.sponsorshipCukurova Universityen_US
dc.description.sponsorshipWe would like to thank Research Fund of Cukurova University for supporting this project.en_US
dc.identifier.doi10.1080/10426500902754278
dc.identifier.endpage170en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-74949105838en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage165en_US
dc.identifier.urihttps://doi.org/10.1080/10426500902754278
dc.identifier.urihttps://hdl.handle.net/11616/94959
dc.identifier.volume185en_US
dc.identifier.wosWOS:000277651900020en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and The Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcetophenoneen_US
dc.subjectaminomethylphosphineen_US
dc.subjecthydrogenationen_US
dc.subjectsilicaen_US
dc.titleHYDROGENATION OF ACETOPHENONE AND ITS DERIVATIVES WITH 2-PROPANOL USING AMINOMETHYLPHOSPHINE-RUTHENIUM CATALYSISen_US
dc.typeArticleen_US

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