Potential N-Heterocyclic Carbene Precursors in the Palladium-Catalyzed Heck Reaction

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dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorDemir, Serpil
dc.contributor.authorZengin, Rukiye
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:37:23Z
dc.date.available2024-08-04T20:37:23Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA novel 1-(cyclobutylmethyl)-substi-tuted imidazolidinium/benzimidazolium salts as N-heterocyclic carbene (NHC) precursors were successfully synthesized and characterized by 1H NMR, 13C NMR, IR, and elemental analysis techniques. These compounds were easily prepared from the reaction of N-alkyl imidazoline/N-alkyl benzimidazole with bromomethylcyclobutane in high yields. The in situ formed catalytic system derived from the NHC precursor and Pd(OAc)2 was used in the Heck reaction between aryl halides and styrene with potassium hydroxide in water. The corresponding Heck products were obtained in good yields. (c) 2012 Wiley Periodicals, Inc. Heteroatom Chem 24:7783, 2013; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21065en_US
dc.description.sponsorshipInonu University Research Fund [IUBAP 2011/142]en_US
dc.description.sponsorshipContract grant sponsor: Inonu University Research Fund.; Contract grant number: IUBAP 2011/142.en_US
dc.identifier.doi10.1002/hc.21065
dc.identifier.endpage83en_US
dc.identifier.issn1042-7163
dc.identifier.issn1098-1071
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84872263142en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage77en_US
dc.identifier.urihttps://doi.org/10.1002/hc.21065
dc.identifier.urihttps://hdl.handle.net/11616/95919
dc.identifier.volume24en_US
dc.identifier.wosWOS:000313592200011en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofHeteroatom Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCross-Coupling Reactionen_US
dc.subjectAryl Chloridesen_US
dc.subjectAqueous-Mediaen_US
dc.subjectOlefin Metathesisen_US
dc.subjectCoordination Chemistryen_US
dc.subjectBenzimidazolium Saltsen_US
dc.subjectSuzuki Reactionen_US
dc.subjectWateren_US
dc.subjectLigandsen_US
dc.subjectComplexesen_US
dc.titlePotential N-Heterocyclic Carbene Precursors in the Palladium-Catalyzed Heck Reactionen_US
dc.typeArticleen_US

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