Palladium(II)-N-heterocyclic carbene-catalyzed direct C2-or C5-arylation of thiazoles with aryl bromides

Basit Öğe Kaydı
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.contributor.authorKaloglu, Murat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:27Z
dc.date.available2024-08-04T20:44:27Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractHerein we report a series of new benzimidazolium chlorides as N-heterocyclic carbene (NHC) ligand and their corresponding palladium(II)-NHC complexes with the general formula [PdCl2(NHC)(2)] were synthesized. All new compounds were characterized by H-1 NMR, C-13 NMR, IR spectroscopy and elemental analysis techniques. The catalytic activity of palladium(II)-NHC complexes was investigated in the direct C2- or C5-arylation of thiazoles with aryl bromides in presence of palladium(II)-NHC at 150(degrees)C for 1 h. These complexes exhibited the good catalytic performance for the direct arylation of thiazoles. The arylation of thiazoles regioselectively produced C2- or C5-arylated thiazoles in moderate to high yields. (C) 2018 Published by Elsevier Ltd.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS [109T605]; Inonu University Research Fund [I.U. B.A.P. 2015/41]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (109T605) and the Inonu University Research Fund (I.U. B.A.P. 2015/41).en_US
dc.identifier.doi10.1016/j.tet.2018.03.026
dc.identifier.endpage2845en_US
dc.identifier.issn0040-4020
dc.identifier.issue23en_US
dc.identifier.scopus2-s2.0-85046352463en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2837en_US
dc.identifier.urihttps://doi.org/10.1016/j.tet.2018.03.026
dc.identifier.urihttps://hdl.handle.net/11616/98265
dc.identifier.volume74en_US
dc.identifier.wosWOS:000432758900003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectBenzimidazolium halideen_US
dc.subjectPalladiumen_US
dc.subjectThiazoleen_US
dc.subjectDirect arylationen_US
dc.titlePalladium(II)-N-heterocyclic carbene-catalyzed direct C2-or C5-arylation of thiazoles with aryl bromidesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu