Five complexes containing N,N-bis(2-hydroxyethyl)-ethylenediamine with tetracyanidopalladate(II): synthesis, crystal structures, thermal, magnetic, and catalytic properties

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dc.authoridAndac, Omer/0000-0003-3641-9690
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKorkmaz, Nesrin/0000-0002-7896-1042
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridKaradag, Ahmet/0000-0003-4676-683X
dc.authorwosidAndac, Omer/A-4035-2016
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidKorkmaz, Nesrin/AAB-3851-2020
dc.authorwosidKORKMAZ, ŞENGÜL ASLAN/ABG-5160-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKorkmaz, S. Aslan
dc.contributor.authorKaradag, A.
dc.contributor.authorKorkmaz, N.
dc.contributor.authorAndac, O.
dc.contributor.authorGurbuz, N.
dc.contributor.authorOzdemir, I.
dc.contributor.authorTopkaya, R.
dc.date.accessioned2024-08-04T20:37:48Z
dc.date.available2024-08-04T20:37:48Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractFive cyanide complexes, [Ni(N-bishydeten)Pd(CN)(4)] (1), [Cu(N-bishydeten)Pd(-CN)(2)(CN)(2)](n) (2), [Cu(N-bishydeten)(2)][Pd(CN)(4)] (3), [Zn(N-bishydeten)Pd(CN)(4)] (4), and [Cd(N-bishydeten)(2)][Pd(CN)(4)] (5) (N-bishydeten = N,N-bis(2-hydroxyethyl)-ethylenediamine), have been synthesized and characterized using various techniques. Different structures were formed when the M:L ratio was varied in copper complexes. The single-crystal X-ray diffraction analysis reveals that 2, a 1-D cyanide-bridged complex with 2,2-CT-type zigzag chain, was obtained by using 1:1M:L ratio whereas 3 was formed as a complex salt in a molar ratio of 1:2. The thermal stabilities determined from DTG(max) values of the first decomposition stages change in the order 1>5>4>3>2. Although an EPR signal was not observed for 1, the g parameters obtained from the EPR spectra of 2 and 3 indicate that Cu-II ions are located in tetragonally distorted octahedral sites (D-4h), and the ground state of the unpaired electron is (B-2(1g)). The magnetic behavior indicates a very small antiferromagnetic interaction below 10K for 1-3. In 3, there is a temperature-independent paramagnetism () due to the orbital moments of the d electrons. 1-3 were tested as catalysts in Suzuki and Heck coupling reactions.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [TBAG-104T205]; Gaziosmanpasa University Research Foundation [2010/110]en_US
dc.description.sponsorshipThe authors thank the Scientific and Technical Research Council of Turkey (TUBITAK, Grant TBAG-104T205) and the Gaziosmanpasa University Research Foundation (Grant 2010/110) for financial support.en_US
dc.identifier.doi10.1080/00958972.2013.820827
dc.identifier.endpage3091en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue17en_US
dc.identifier.scopus2-s2.0-84883530731en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3072en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2013.820827
dc.identifier.urihttps://hdl.handle.net/11616/96194
dc.identifier.volume66en_US
dc.identifier.wosWOS:000323312600012en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTetracyanidopalladateen_US
dc.subjectNen_US
dc.subjectN-bis(2-hydroxyethyl)-ethylenediamineen_US
dc.subjectThermal analysisen_US
dc.subjectMagnetic susceptibilityen_US
dc.subjectSuzuki-Heck coupling reactionen_US
dc.titleFive complexes containing N,N-bis(2-hydroxyethyl)-ethylenediamine with tetracyanidopalladate(II): synthesis, crystal structures, thermal, magnetic, and catalytic propertiesen_US
dc.typeArticleen_US

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