Dichloride[1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl) -imidazolidin-2-ylidine (?6-hexamethylbenzene)]ruthenium
dc.authorscopusid | 57200576372 | |
dc.authorscopusid | 15126376900 | |
dc.authorscopusid | 7005334934 | |
dc.authorscopusid | 57201214280 | |
dc.authorscopusid | 7006471258 | |
dc.contributor.author | Arslan H. | |
dc.contributor.author | Van Derveer D. | |
dc.contributor.author | Özdemir I. | |
dc.contributor.author | Yaşar S. | |
dc.contributor.author | Çetinkaya B. | |
dc.date.accessioned | 2024-08-04T20:00:56Z | |
dc.date.available | 2024-08-04T20:00:56Z | |
dc.date.issued | 2006 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) Å, b = 14.4447(27) Å, c = 27.4325(52) Å, and V = 6878.466(4) Å3 with Z = 8 for Dcalc = 1.357 g/cm3. It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the ?6-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral. © TÜBİTAK. | en_US |
dc.identifier.endpage | 541 | en_US |
dc.identifier.issn | 1300-0527 | |
dc.identifier.issue | 5 | en_US |
dc.identifier.scopus | 2-s2.0-33845313585 | en_US |
dc.identifier.scopusquality | Q3 | en_US |
dc.identifier.startpage | 535 | en_US |
dc.identifier.uri | https://hdl.handle.net/11616/91131 | |
dc.identifier.volume | 30 | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Arenes | en_US |
dc.subject | Carbenes | en_US |
dc.subject | Imidazole | en_US |
dc.subject | Ruthenium complex | en_US |
dc.subject | X-ray structure | en_US |
dc.title | Dichloride[1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl) -imidazolidin-2-ylidine (?6-hexamethylbenzene)]ruthenium | en_US |
dc.type | Article | en_US |