Direct arylation of heteroaromatic compounds by Pd(OAc)2/tetrakis(N-benzimidazoliummethyl)benzene salt system
Küçük Resim Yok
Tarih
2021
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Arkat Usa Inc
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Six novel tetrakis(N-benzimidazoliummethyl)benzene salts were synthesized using 1,2,4,5-tetrakis(bromomethyl)benzene with 1-alkylbenzimidazole. The structures of all isolated compounds were elucidated based on spectroscopic methods (H-1 and C-13 NMR, and FT-IR spectroscopy) and were investigated for their catalytic activities in the direct arylation of 2-n-propylthiazole, 2-n-buthyltiophene, 2-n-butylfuran, and 4,5dimethylthiazole. All synthesized salts showed high catalytic activity for direct arylation of heteroaromatic compounds. [GRAPHICS]
Açıklama
Anahtar Kelimeler
Palladium, catalytic activity, direct arylation, N-heterocyclic carbene
Kaynak
Arkivoc
WoS Q Değeri
Q4
Scopus Q Değeri
Q4