RHODIUM(I)-N-HETEROCYCLIC CARBENE-CATALYZED ADDITION OF SODIUM TETRAPHENYLBORATE TO KETONES TO FORM TERTIARY ALCOHOLS

Küçük Resim Yok

Tarih

2014

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Pergamon-Elsevier Science Ltd

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Rhodium complexes ([Rh(COD)(NHC)Cl]) were synthesized by the reaction of bis(1,3-dialkylperhydrobenzimidazolin-2-ylidene) with [RhClCOD](2) in toluene and characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. These complexes were used as catalysts for the addition of sodium tetraphenylborate to aromatic ketones and corresponding tertiary alcohols were obtained in good yields.

Açıklama

Anahtar Kelimeler

Rhodium Complex, NHC Ligand, Arylation Reaction, Alcohol, Ketone

Kaynak

Heterocycles

WoS Q Değeri

Q3

Scopus Q Değeri

Q4

Cilt

89

Sayı

11

Künye