RHODIUM(I)-N-HETEROCYCLIC CARBENE-CATALYZED ADDITION OF SODIUM TETRAPHENYLBORATE TO KETONES TO FORM TERTIARY ALCOHOLS
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Date
2014
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Pergamon-Elsevier Science Ltd
Access Rights
info:eu-repo/semantics/openAccess
Abstract
Rhodium complexes ([Rh(COD)(NHC)Cl]) were synthesized by the reaction of bis(1,3-dialkylperhydrobenzimidazolin-2-ylidene) with [RhClCOD](2) in toluene and characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. These complexes were used as catalysts for the addition of sodium tetraphenylborate to aromatic ketones and corresponding tertiary alcohols were obtained in good yields.
Description
Keywords
Rhodium Complex, NHC Ligand, Arylation Reaction, Alcohol, Ketone
Journal or Series
Heterocycles
WoS Q Value
Q3
Scopus Q Value
Q4
Volume
89
Issue
11
