RHODIUM(I)-N-HETEROCYCLIC CARBENE-CATALYZED ADDITION OF SODIUM TETRAPHENYLBORATE TO KETONES TO FORM TERTIARY ALCOHOLS
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Rhodium complexes ([Rh(COD)(NHC)Cl]) were synthesized by the reaction of bis(1,3-dialkylperhydrobenzimidazolin-2-ylidene) with [RhClCOD](2) in toluene and characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. These complexes were used as catalysts for the addition of sodium tetraphenylborate to aromatic ketones and corresponding tertiary alcohols were obtained in good yields.
Açıklama
Anahtar Kelimeler
Rhodium Complex, NHC Ligand, Arylation Reaction, Alcohol, Ketone
Kaynak
Heterocycles
WoS Q Değeri
Q3
Scopus Q Değeri
Q4
Cilt
89
Sayı
11
