Palladium(II)-N-Heterocyclic Carbene Complexes: Efficient Catalysts for the Direct C-H Bond Arylation of Furans with Aryl Halides

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dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKaloglu, Murat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:27Z
dc.date.available2024-08-04T20:44:27Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis paper contains the synthesis and characterization of the seven new benzimidazolium salts and their corresponding new palladium(II)-NHC complexes with the general formula [PdX2(NHC)(2)], (NHC=N-heterocyclic carbene, X=Cl or Br), and also their catalytic activity in direct C-H bond arylation of 2-substituted furan derivatives with aryl bromides and aryl chlorides. Under the optimal conditions, these palladium(II)-NHC complexes showed the good catalytic performance for the direct C-H bond arylation of 2-substituted furans with (hetero)aryl bromides, and with readily available and inexpensive aryl chlorides. The C-H bond arylation regioselectively produced C5-arylated furans by using 1mol% of the palladium(II)-NHC catalysts in moderate to high yields.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK) [109T605]; Inonu University Research Fund (I.U. B.A.P.) [2015/41]en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK), Grant/Award Number: 109T605; Inonu University Research Fund (I.U. B.A.P.), Grant/Award Number: 2015/41en_US
dc.identifier.doi10.1002/aoc.4399
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85046036779en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.4399
dc.identifier.urihttps://hdl.handle.net/11616/98255
dc.identifier.volume32en_US
dc.identifier.wosWOS:000435929700025en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectbenzimidazolium salten_US
dc.subjectdirect C-H bond arylationen_US
dc.subjectfuranen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectpalladiumen_US
dc.titlePalladium(II)-N-Heterocyclic Carbene Complexes: Efficient Catalysts for the Direct C-H Bond Arylation of Furans with Aryl Halidesen_US
dc.typeArticleen_US

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