Anti-Markovnikov hydroaminations of styrene catalyzed by palladium(II) N-heterocyclic carbene complexes under conventional and microwave heating
Küçük Resim Yok
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Six palladium(II) complexes with benzimidazole-based N-heterocyclic carbene ligands were synthesized by transmetallation reactions between silver(I) N-heterocyclic carbene complexes and PdCl2(PhCN)(2). The complexes were characterized by physicochemical and spectroscopic methods. The palladium complexes were tested as catalysts for intermolecular hydroamination reactions of styrene with various anilines in ionic liquids under both conventional and microwave heating. All of these complexes proved to be catalytically active in these reactions. The anti-Markovnikov addition products were selectively obtained by using 1 mol% of the palladium complex.
Açıklama
Anahtar Kelimeler
Intermolecular Hydroamination, Ionic Liquid, Alkenes, Vinylarenes, Arylamines, Alkaloids, Pyrrole, Systems
Kaynak
Transition Metal Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q2
Cilt
43
Sayı
7
