Dichlorido[1-(2-methylbenzyl)-3-(?6-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate

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dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorArslan, Hakan
dc.contributor.authorVanDerveer, Don
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:31:08Z
dc.date.available2024-08-04T20:31:08Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe title complex, [RuCl2(C25H26N2)]center dot CH2Cl2, is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C6H2(CH3)(3) arene group by a CH2 bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C-center dot center dot center dot N and C-H center dot center dot center dot Cl interactions.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS [TBAG-U/181(106 T716)]; Inonu University Research Fund [BAP 2007/39]en_US
dc.description.sponsorshipWe thank the Technological and Scientific Research Council of Turkey TUBITAK-CNRS [grant No. TBAG-U/181(106 T716)] and Inonu University Research Fund (BAP 2007/39) for financial support.en_US
dc.identifier.doi10.1107/S160053680900350X
dc.identifier.endpageU167en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21582038en_US
dc.identifier.scopus2-s2.0-62149149606en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM243en_US
dc.identifier.urihttps://doi.org/10.1107/S160053680900350X
dc.identifier.urihttps://hdl.handle.net/11616/94761
dc.identifier.volume65en_US
dc.identifier.wosWOS:000264796100008en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectAlkene Metathesisen_US
dc.subjectComplexesen_US
dc.subjectCycloisomerizationen_US
dc.subjectCatalysisen_US
dc.titleDichlorido[1-(2-methylbenzyl)-3-(?6-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvateen_US
dc.typeArticleen_US

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