Synthesis of melt-quenched Bi1.7V0.3Sr2Ca2Cu3O10+y superconducting glass-ceramics

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dc.contributor.authorYakinci, ME
dc.contributor.authorAksoy, I
dc.contributor.authorCeylan, M
dc.date.accessioned2024-08-04T20:11:51Z
dc.date.available2024-08-04T20:11:51Z
dc.date.issued1996
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA glass in the BSCCO system with Bi1.7V0.3Sr2Ca2Cu3O10+y nominal composition was prepared by the melt-quenching (glass) method. The suitability of the glass ceramic method has been assessed in terms of physical and electrical properties. Using an analysis developed for non-isothermal crystallization studies, information on some aspects of crystallization has been obtained. The result obtained indicated that substitution of vanadium for bismuth increased the activation energy compared to the unsubstituted BSCCO system but did not enhance the superconducting phase formation. The activation energy for crystallization of glass has been found, E(a)=355 kJ mol(-1). The crystal structure was found to differ from that in the unsubstituted BSCCO system. Most importantly, the HT, phase was formed by reaction between the constituent phases at lower temperatures and not directly from the glass material. The best electrical properties were obtained at T-0=75 K and J(c)=12 x 10(3) A cm(-2) at 4.2 K.en_US
dc.identifier.doi10.1007/BF00355994
dc.identifier.endpage2871en_US
dc.identifier.issn0022-2461
dc.identifier.issn1573-4803
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-0030171473en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2865en_US
dc.identifier.urihttps://doi.org/10.1007/BF00355994
dc.identifier.urihttps://hdl.handle.net/11616/93039
dc.identifier.volume31en_US
dc.identifier.wosWOS:A1996UT35500011en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Materials Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCu-O Systemen_US
dc.subjectCrystallizationen_US
dc.titleSynthesis of melt-quenched Bi1.7V0.3Sr2Ca2Cu3O10+y superconducting glass-ceramicsen_US
dc.typeArticleen_US

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