The electrochemical properties of V-doped Li2Ti6O13 and Na2Ti6O13 anode materials

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dc.authoridDemirel, Serkan/0000-0003-1158-4956
dc.authoridALTIN, Serdar/0000-0002-4590-907X
dc.authorwosidDemirel, Serkan/AAA-2133-2020
dc.authorwosidALTIN, Serdar/H-4880-2014
dc.contributor.authorDemirel, S.
dc.contributor.authorAltin, S.
dc.date.accessioned2024-08-04T20:45:34Z
dc.date.available2024-08-04T20:45:34Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractLi2Ti6-xVxO13 and Na2Ti6-xVxO13 (where x = 0, 0.025, 0.05, 0.1) are prepared by conventional ion exchange method and solid-state reaction technique, respectively. According to XRD analysis, increasing V contents in the structures cause the formation of LiVO3 and LiV3O8 phases for x >= 0.025 substitutions for Li2Ti6O13 and Na4V2O7 in structure for Na2Ti6O13 x >= 0.025. It was observed two redox peaks for both undoped compositions which are related to insertion and deinsertion of Li/Na ions in the structure. The battery performances were investigated for Li2Ti6-xVxO13 and Na2Ti6-xVxO13 systems and it is found that pure Li2Ti6O13 sample has showed the capacity of 36 mAh g(-1) and 27 mAh g(-1) for 1 and 1000 cycle respectively which show better capacity fade when compared with the other anode materials. The battery performance of undoped Na2Ti6O13 sample has 40 mAh g(-1) and 34 mAh g(-1) for 1 and 1000 cycle respectively. In addition to this, the x = 0.05 V-substitution has showed 66 mAh g(-1) for the first cycle which is higher than that of the undoped sample. It was investigated the structural deformation of the cells by in situ XRD during to CV process and ex situ XRD and Raman techniques after cycling of the cells. It is predicted that the changes of the reflection planes of the crystallites/grains during to cycling of the cells may be the main reason of the decrease of the battery performance which is related to insertion and de-insertion energy of the Li-ions.en_US
dc.description.sponsorshipInonu University Research Council [BAP-2015/85]; TUBITAK 2214-A International scholar ship programen_US
dc.description.sponsorshipThis project was supported by Inonu University Research Council with contract number of BAP-2015/85. Dr S. Demirel was supported by TUBITAK 2214-A International scholar ship program for studying in the University of Illinois Material Science and Engineering Department for performing the experimental work in Braun Research group. Dr Serkan Demirel wants to thank Prof. Paul V. Braun for allowing using of the laboratory.en_US
dc.identifier.doi10.1088/2053-1591/aaf2b3
dc.identifier.issn2053-1591
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85058185764en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1088/2053-1591/aaf2b3
dc.identifier.urihttps://hdl.handle.net/11616/98568
dc.identifier.volume6en_US
dc.identifier.wosWOS:000518690600002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherIop Publishing Ltden_US
dc.relation.ispartofMaterials Research Expressen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectLi2Ti6O13 and Na2Ti6O13en_US
dc.subjection exchangeen_US
dc.subjectbattery performanceen_US
dc.titleThe electrochemical properties of V-doped Li2Ti6O13 and Na2Ti6O13 anode materialsen_US
dc.typeArticleen_US

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