Magnetite@MCM-41 nanoparticles as support material for Pd-N-heterocyclic carbene complex: A magnetically separable catalyst for Suzuki-Miyaura reaction

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dc.authoridAKKOÇ, Mitat/0000-0001-8641-8958
dc.authoridBugday, Nesrin/0000-0002-3882-035X
dc.authoridAltin, Serdar/0000-0002-4590-907X
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authorwosidAKKOÇ, Mitat/AAJ-5780-2020
dc.contributor.authorAkkoc, Mitat
dc.contributor.authorBugday, Nesrin
dc.contributor.authorAltin, Serdar
dc.contributor.authorYasar, Sedat
dc.date.accessioned2024-08-04T20:49:24Z
dc.date.available2024-08-04T20:49:24Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe Magnetite@MCM-41@NHC@Pd catalyst was obtained with Pd metal bound to the NHC ligand anchored to the surface of Fe3O4@MCM-41. It was characterized by Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy disperse X-ray analysis (EDX), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy (SEM). The amount of Pd in the Magnetite@MCM-41@NHC@Pd was measure by inductively coupled plasma-optical emission spectroscopy (ICP-OES) analysis. The catalytic activity of Magnetite@MCM-41@NHC@Pd heterogeneous catalyst done on Suzuki-Miyaura reactions of aryl halides with different substituted arylboronic acid derivatives. All coupling reactions afforded excellent yields and up to 408404 Turnover Frequency (TOF) h(-1) in the presence of 2 mg of Magnetite@MCM-41@NHC@Pd catalyst (0.0564 mmol g(-1), 0.01127 mmol% Pd) at room temperature in 2-propanol/H2O (1:2). Moreover, Magnetite@MCM-41@NHC@Pd catalyst was recover by applying the magnet and reused for another reaction. The catalyst showed excellent structural and chemical stability and reused ten times without a substantial loss in its catalytic performance.en_US
dc.description.sponsorshipNFFA-Europe Transnational Access Activity (NFFA Project) [723]en_US
dc.description.sponsorshipXPS and TEM studies were performed in France (CEA LETI/DTSI/SCMC Grenoble Cedex 9 FRANCE and thanks to N. GAMBACORTI for organization of XPS and TEM analysis) within the framework of the NFFA-Europe Transnational Access Activity (NFFA Project ID: 723).en_US
dc.identifier.doi10.1002/aoc.6233
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85102638552en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.6233
dc.identifier.urihttps://hdl.handle.net/11616/99825
dc.identifier.volume35en_US
dc.identifier.wosWOS:000629789400001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectmagnetic palladium catalysten_US
dc.subjectmagnetiteen_US
dc.subjectMCM? 41en_US
dc.subjectPd (II)? N? heterocyclic carbeneen_US
dc.subjectSuzuki– Miyaura reactionen_US
dc.titleMagnetite@MCM-41 nanoparticles as support material for Pd-N-heterocyclic carbene complex: A magnetically separable catalyst for Suzuki-Miyaura reactionen_US
dc.typeArticleen_US

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