Highly Efficient Single A3-Coupling (Aldehyde-Amine-Alkyne) Reaction Catalyzed by Air Stable Silver-(N-Heterocyclic Carbene) Complexes: Synthesis and Characterization

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKhan, Tariq Ayub/0000-0001-6184-5929
dc.authorwosidNasr, Ibrahim Al/AFP-8105-2022
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorHamdi, Naceur
dc.contributor.authorMnasri, Aziza
dc.contributor.authorS. Al Nasr, Ibrahim
dc.contributor.authorS. Koko, Waleed
dc.contributor.authorKhan, Tariq A.
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorGurbuz, Nevin
dc.date.accessioned2024-08-04T20:51:35Z
dc.date.available2024-08-04T20:51:35Z
dc.date.issued2022
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe interaction of N,N-disubstituted benzimidazolium salts 2a-e with Ag2O formed new silver-(N-heterocyclic carbene) complexes 3a-e. Structural characterization of silver-(N-heterocyclic carbene) complexes was conducted by using NMR, FT-IR and elemental analysis. Preliminary catalytic studies using all the silver complexes 3a-e were performed on three-component coupling reaction of a series of aldehydes with alkynes and amines was demonstrated. Most of these reactions led to formation of the expected propargylamines in good conversions using low amounts catalyst and obviating both the use of purified reagents as employ of a glovebox. Complexes 3a and 3c exhibited good catalytic activities under neat conditions. The silver complexes 3a-e showed luminescence properties in CH3CN at room temperature.en_US
dc.description.sponsorshipQassim University [10124-cosao-2020-1-3-I]en_US
dc.description.sponsorshipThe authors gratefully acknowledge Qassim University, represented by the Deanship of Scientific Research, on the financial support for this research under the number (10124-cosao-2020-1-3-I) during the academic year 1442AH/2020AD.en_US
dc.identifier.doi10.1080/10406638.2021.2019064
dc.identifier.issn1040-6638
dc.identifier.issn1563-5333
dc.identifier.scopus2-s2.0-85122934280en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1080/10406638.2021.2019064
dc.identifier.urihttps://hdl.handle.net/11616/100417
dc.identifier.wosWOS:000744310000001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPolycyclic Aromatic Compoundsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMulticomponent reactionen_US
dc.subjectone pot reactionen_US
dc.subjectA(3)-coupling reactionen_US
dc.subjectpropargylaminesen_US
dc.subjectketonesen_US
dc.subjectaminesen_US
dc.subjectalkynesen_US
dc.subjectsilver complexesen_US
dc.titleHighly Efficient Single A3-Coupling (Aldehyde-Amine-Alkyne) Reaction Catalyzed by Air Stable Silver-(N-Heterocyclic Carbene) Complexes: Synthesis and Characterizationen_US
dc.typeArticleen_US

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