Dichlorido(3-chloropyridine-N)[1,3-dialkylbenzimidazol-2-ylidene] palladium(II) complexes: Synthesis, characterization and catalytic activity in the arylation reaction

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dc.authoridAkkoc, Senem/0000-0002-1260-9425
dc.authorwosidAkkoç, Senem/AAN-1478-2021
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorAkkoc, Senem
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:40:04Z
dc.date.available2024-08-04T20:40:04Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSix novel Pyridine Enhanced Precatalyst Preparation, Stabilization and Initiation (PEPPSI) themed palladium N-heterocyclic carbene (Pd-NHC) complexes (2a-f) were synthesized in good yields from the reaction of 1,3-dialkylbenzimidazolium salts with PdCl2 in the presence of K2CO3 as base in 3-chloropyridine. These synthesized complexes were characterized by means of elemental analysis, FT-IR, H-1 and C-13 NMR spectroscopic methods. The fully characterized novel complexes (2a-f) were tested as catalysts in the direct arylation of 2-n-propylthiazole, 2-n-butylthiophene and 2-n-butylfuran with different aryl bromides at 130 degrees C for 1 h. The complexes exhibited fairly high catalytic activities under the given conditions. The highest conversions were achieved when complexes 2a, 2e and 2f were used as catalysts in direct arylation. (C) 2015 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipErciyes University in Kayseri; Inonu University in Malatyaen_US
dc.description.sponsorshipWe would like to thank to Erciyes University in Kayseri and Inonu University in Malatya for their financial support.en_US
dc.identifier.doi10.1016/j.ica.2015.01.019
dc.identifier.endpage38en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84923171795en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage34en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2015.01.019
dc.identifier.urihttps://hdl.handle.net/11616/96690
dc.identifier.volume429en_US
dc.identifier.wosWOS:000350996800005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPEPPSI palladium complexesen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectBenzimidazoleen_US
dc.subjectCatalysten_US
dc.subjectDirect arylationen_US
dc.titleDichlorido(3-chloropyridine-N)[1,3-dialkylbenzimidazol-2-ylidene] palladium(II) complexes: Synthesis, characterization and catalytic activity in the arylation reactionen_US
dc.typeArticleen_US

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