1-(2-Phenylbenzyl)-3-(2,4,6-trimethylbenzyl)imidazolidinium bromide

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dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorArslan, Hakan
dc.contributor.authorVanDerveer, Don
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Smail
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:31:06Z
dc.date.available2024-08-04T20:31:06Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn the title salt, C(26)H(29)N(2)(+)center dot Br(-),which may serve as a precursor for N-heterocyclic carbenes, the imidazolidine ring adopts a twist conformation with a pseudo-twofold axis passing through the N-C-N carbon and the opposite C-C bond. The N-C-N bond angle [113.0 (4)degrees] and C-N bond lengths [1.313 (6) and 1.305 (6) angstrom] confirm the existence of strong resonance in this part of the molecule. In the crystal, a C-H center dot center dot center dot Br interaction is present. The dihedral angle between the biphenyl rings is 64.3 (2)degrees and the phenyl rings make angles of 76.6 (3) and 18.5 (3)degrees with the plane of the imidazolidine ring.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [TUBITAK(106T106)]; Inonu University Research Fund [BAP:2006/Gudumlu-7]en_US
dc.description.sponsorshipThis work was supported financially by the Technological and Scientific Research Council of Turkey TUBITAK [TUBITAK(106T106)] and Inonu University Research Fund BAP:2006/Gudumlu-7).en_US
dc.identifier.doi10.1107/S1600536808042086
dc.identifier.endpageU2308en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21581583en_US
dc.identifier.scopus2-s2.0-58149461528en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageO121en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536808042086
dc.identifier.urihttps://hdl.handle.net/11616/94729
dc.identifier.volume65en_US
dc.identifier.wosWOS:000262234500201en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwell Publishing, Incen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectCrystal-Structureen_US
dc.subjectSuzuki Reactionen_US
dc.subjectAryl Chloridesen_US
dc.subjectAqueous-Mediaen_US
dc.subjectLigandsen_US
dc.subjectSaltsen_US
dc.subjectCatalysisen_US
dc.subjectComplexen_US
dc.subjectBonden_US
dc.title1-(2-Phenylbenzyl)-3-(2,4,6-trimethylbenzyl)imidazolidinium bromideen_US
dc.typeArticleen_US

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