Fabrication of a Stable and Highly Effective Anode Material for Li-Ion/Na-Ion Batteries Utilizing ZIF-12

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dc.contributor.authorBugday, Nesrin
dc.contributor.authorWang, Haoji
dc.contributor.authorHong, Ningyun
dc.contributor.authorZhang, Baichao
dc.contributor.authorDeng, Wentao
dc.contributor.authorZou, Guoqiang
dc.contributor.authorHou, Hongshuai
dc.date.accessioned2024-08-04T20:56:12Z
dc.date.available2024-08-04T20:56:12Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractTransition metal selenides (TMSs) are receiving considerable interest as improved anode materials for sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs) due to their considerable theoretical capacity and excellent redox reversibility. Herein, ZIF-12 (zeolitic imidazolate framework) structure is used for the synthesis of Cu2Se/Co3Se4@NPC anode material by pyrolysis of ZIF-12/Se mixture. When Cu2Se/Co3Se4@NPC composite is utilized as an anode electrode material in LIB and SIB half cells, the material demonstrates excellent electrochemical performance and remarkable cycle stability with retaining high capacities. In LIB and SIB half cells, the Cu2Se/Co3Se4@NPC anode material shows the ultralong lifespan at 2000 mAg-1, retaining a capacity of 543 mAhg-1 after 750 cycles, and retaining a capacity of 251 mAhg-1 after 200 cycles at 100 mAg-1, respectively. The porous structure of the Cu2Se/Co3Se4@NPC anode material can not only effectively tolerate the volume expansion of the electrode during discharging and charging, but also facilitate the penetration of electrolyte and efficiently prevents the clustering of active particles. In situ X-ray difraction (XRD) analysis results reveal the high potential of Cu2Se/Co3Se4@NPC composite in building efficient LIBs and SIBs due to reversible conversion reactions of Cu2Se/Co3Se4@NPC for lithium-ion and sodium-ion storage. The Cu2Se/Co3Se4@NPC material, which is synthesized from Cu@ZIF-12, utilizes the advantages of Cu and Co metal complexes to facilitate the storage of lithium and sodium ions. Defect-rich N-doped amorphous carbon (NPC) improves electrical conductivity, and the Cu2Se/Co3Se4@NPC composite material demonstrates remarkable cycle stability while retaining high capacities in LIB and SIB half cells. imageen_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBIdot;TAK) [122N559]; BAP Unit of Idot;noenue University [FDK-2023-3311]; Department of Science Fellowships and Grant Programs (TUBIdot;TAK, BIdot;DEB) [2214-A]en_US
dc.description.sponsorshipThis study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) under Grant Number 122N559, the BAP Unit of & Idot;noenue University with the project number FDK-2023-3311, and N. Bugday was supported by Department of Science Fellowships and Grant Programs (TUB & Idot;TAK, B & Idot;DEB, 2214-A) for studyingin the Central South University, College of Chemistry and Chemical Engineering. The authors thank TUBITAK for their support.en_US
dc.identifier.doi10.1002/smll.202403736
dc.identifier.issn1613-6810
dc.identifier.issn1613-6829
dc.identifier.pmid38990899en_US
dc.identifier.scopus2-s2.0-85198091469en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1002/smll.202403736
dc.identifier.urihttps://hdl.handle.net/11616/102111
dc.identifier.wosWOS:001266006900001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofSmallen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectanodeen_US
dc.subjectCu-ZIF-12en_US
dc.subjectin situ XRDen_US
dc.subjectLi-ion/Na-ion batteriesen_US
dc.subjectmetal selenideen_US
dc.subjectZIF-12en_US
dc.titleFabrication of a Stable and Highly Effective Anode Material for Li-Ion/Na-Ion Batteries Utilizing ZIF-12en_US
dc.typeArticleen_US

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