Direct CH Bond Activation of Benzoxazole and Benzothiazole with Aryl Bromides Catalyzed by Palladium(II)-N-heterocyclic Carbene Complexes

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dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKaloglu, Murat
dc.contributor.authorKaloglur, Nazan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:40Z
dc.date.available2024-08-04T20:44:40Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractHerein, we report that a series of novel palladium(II)-NHC complexes (NHC=N-heterocyclic carbene) were synthesized. The structures of all novel complexes were characterized by H-1 NMR, C-13 NMR, FT-IR spectroscopy and elemental analysis techniques. These palladium(II)-NHC complexes were tested as efficient catalysts in the direct CH bond activation of benzoxazole and benzothiazole with aryl bromides in the presence of 1 mol% catalyst loading at 150 degrees C for 4 h. Under the given conditions, various aryl bromides were successfully applied as the arylating reagents to achieve the 2-arylbenzoxazoles and 2-arylbenzothiazoles in acceptable to high yields.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France)) [109T605]; Inonu University Research Fund (IUBAP) [2015/41]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France), Project No.: 109T605) and the Inonu University Research Fund (IUBAP, Project No.: 2015/41).en_US
dc.identifier.doi10.1002/cjoc.201800166
dc.identifier.endpage844en_US
dc.identifier.issn1001-604X
dc.identifier.issn1614-7065
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-85050456640en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage837en_US
dc.identifier.urihttps://doi.org/10.1002/cjoc.201800166
dc.identifier.urihttps://hdl.handle.net/11616/98393
dc.identifier.volume36en_US
dc.identifier.wosWOS:000441435300008en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChinese Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectbenzimidazolium bromideen_US
dc.subjectbenzoazolesen_US
dc.subjectdirect CH bond activationen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectpalladiumen_US
dc.titleDirect CH Bond Activation of Benzoxazole and Benzothiazole with Aryl Bromides Catalyzed by Palladium(II)-N-heterocyclic Carbene Complexesen_US
dc.typeArticleen_US

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