Direct CH Bond Activation of Benzoxazole and Benzothiazole with Aryl Bromides Catalyzed by Palladium(II)-N-heterocyclic Carbene Complexes
dc.authorid | Kaloğlu, Murat/0000-0002-2770-5532 | |
dc.authorid | Özdemir, İsmail/0000-0001-6325-0216 | |
dc.authorwosid | Kaloğlu, Murat/AAA-3956-2021 | |
dc.authorwosid | Özdemir, İsmail/ABI-5192-2020 | |
dc.contributor.author | Kaloglu, Murat | |
dc.contributor.author | Kaloglur, Nazan | |
dc.contributor.author | Ozdemir, Ismail | |
dc.date.accessioned | 2024-08-04T20:44:40Z | |
dc.date.available | 2024-08-04T20:44:40Z | |
dc.date.issued | 2018 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | Herein, we report that a series of novel palladium(II)-NHC complexes (NHC=N-heterocyclic carbene) were synthesized. The structures of all novel complexes were characterized by H-1 NMR, C-13 NMR, FT-IR spectroscopy and elemental analysis techniques. These palladium(II)-NHC complexes were tested as efficient catalysts in the direct CH bond activation of benzoxazole and benzothiazole with aryl bromides in the presence of 1 mol% catalyst loading at 150 degrees C for 4 h. Under the given conditions, various aryl bromides were successfully applied as the arylating reagents to achieve the 2-arylbenzoxazoles and 2-arylbenzothiazoles in acceptable to high yields. | en_US |
dc.description.sponsorship | Technological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France)) [109T605]; Inonu University Research Fund (IUBAP) [2015/41] | en_US |
dc.description.sponsorship | This work was financially supported by the Technological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France), Project No.: 109T605) and the Inonu University Research Fund (IUBAP, Project No.: 2015/41). | en_US |
dc.identifier.doi | 10.1002/cjoc.201800166 | |
dc.identifier.endpage | 844 | en_US |
dc.identifier.issn | 1001-604X | |
dc.identifier.issn | 1614-7065 | |
dc.identifier.issue | 9 | en_US |
dc.identifier.scopus | 2-s2.0-85050456640 | en_US |
dc.identifier.scopusquality | Q1 | en_US |
dc.identifier.startpage | 837 | en_US |
dc.identifier.uri | https://doi.org/10.1002/cjoc.201800166 | |
dc.identifier.uri | https://hdl.handle.net/11616/98393 | |
dc.identifier.volume | 36 | en_US |
dc.identifier.wos | WOS:000441435300008 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley-V C H Verlag Gmbh | en_US |
dc.relation.ispartof | Chinese Journal of Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | benzimidazolium bromide | en_US |
dc.subject | benzoazoles | en_US |
dc.subject | direct CH bond activation | en_US |
dc.subject | N-heterocyclic carbene | en_US |
dc.subject | palladium | en_US |
dc.title | Direct CH Bond Activation of Benzoxazole and Benzothiazole with Aryl Bromides Catalyzed by Palladium(II)-N-heterocyclic Carbene Complexes | en_US |
dc.type | Article | en_US |