New (NHC)Pd(II)(PPh3) complexes: synthesis, characterization, crystal structure and its application on Sonogashira and Mizoroki-Heck cross-coupling reactions

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dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.contributor.authorErdemir, Fatos
dc.contributor.authorAktas, Aydin
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:46:03Z
dc.date.available2024-08-04T20:46:03Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, new six Pd-based complexes containing mixture N-heterocyclic carbene (NHC) and triphenylphosphine-(PPh3) ligands were synthesized from the reaction of the (NHC)PdI2(pyridine) with-PPh3. The new (NHC)PdI2(PPh3) complexes were characterized using FTIR, H-1-NMR, C-13-NMR, and P-31-NMR spectroscopy and elemental analyses techniques. These spectra are consistent with the proposed formula. Molecular and crystal structure of two complexes was obtained using single-crystal X-ray diffraction method. Based on the crystal results, a cis geometry was assigned to all the complexes. These new complexes have been examined as the catalyst in the Sonogashira cross-coupling reaction. The catalytic conversions of the complexes were obtained between 71 and 99% from the reaction of phenylacetylene and aryl bromides. Also, these new complexes have been examined as the catalyst in the Mizoroki-Heck cross-coupling reaction. The catalytic conversions of the complexes were obtained between 80 and 100% from the reaction of styrene and aryl bromides.en_US
dc.description.sponsorshipDokuz Eylul University [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Dokuz Eylul University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University Research Grant no.: 2010.KB.FEN.13). The authors thank the Inonu University Faculty of Science Department of Chemistry for the spectroscopy and elemental analysis characterization of compounds.en_US
dc.identifier.doi10.1007/s11696-019-00859-x
dc.identifier.endpage112en_US
dc.identifier.issn2585-7290
dc.identifier.issn1336-9075
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85069180433en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage99en_US
dc.identifier.urihttps://doi.org/10.1007/s11696-019-00859-x
dc.identifier.urihttps://hdl.handle.net/11616/98873
dc.identifier.volume74en_US
dc.identifier.wosWOS:000510432900005en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer International Publishing Agen_US
dc.relation.ispartofChemical Papersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal structureen_US
dc.subjectMizoroki-Heck reactionsen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectPalladium complexen_US
dc.subjectSonogashira reactionsen_US
dc.subjectTriphenylphosphineen_US
dc.titleNew (NHC)Pd(II)(PPh3) complexes: synthesis, characterization, crystal structure and its application on Sonogashira and Mizoroki-Heck cross-coupling reactionsen_US
dc.typeArticleen_US

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