Butylene linked palladium N-heterocyclic carbene complexes: Synthesis and catalytic properties

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidArslan, Hakan/B-1081-2008
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorArslan, Hakan
dc.contributor.authorVanDerveer, Don
dc.date.accessioned2024-08-04T20:32:51Z
dc.date.available2024-08-04T20:32:51Z
dc.date.issued2011
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew bis(NHC)-Pd complexes were synthesized and characterized by elemental analysis, H-1 NMR, C-13 NMR, and IR spectroscopy. The reaction of Pd(OAc)(2) and bis(benzimidazolium) salts in DMSO gave the monomeric palladium complex in which the N-heterocyclic carbene was bound to the metal centre. The crystal and molecular structure of the cis-dibromo{1,1'-di[2,3,4,5,6-pentamethylbenzyl]-3,3'-butylene-dibenzimidazol-2,2'-diylidene}-palladium(II) complex was determined by single-crystal X-ray diffraction. The activity of the Pd(II) complexes in the direct arylation of benzothiazole with arylbromides was investigated. A preliminary catalytic study showed that these bis(NHC)-Pd complexes were highly active in the direct arylation of benzothiazole with arylbromides. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)]; Inonu University [I.U.B.A.P: 2009/10, 2009/13]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)] and Inonu University Research Fund (I.U.B.A.P: 2009/10 and 2009/13).en_US
dc.identifier.doi10.1016/j.jorganchem.2011.03.040
dc.identifier.endpage2593en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue13en_US
dc.identifier.scopus2-s2.0-79957723204en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage2589en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2011.03.040
dc.identifier.urihttps://hdl.handle.net/11616/95342
dc.identifier.volume696en_US
dc.identifier.wosWOS:000291017700019en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChelating N-heterocyclic carbeneen_US
dc.subjectPalladiumen_US
dc.subjectArylationen_US
dc.subjectBenzothiazoleen_US
dc.titleButylene linked palladium N-heterocyclic carbene complexes: Synthesis and catalytic propertiesen_US
dc.typeArticleen_US

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