The direct C(sp2)-H functionalization and coupling of aromatic N-heterocycles with (hetero)aryl bromides by [PdX2(imidazolidin-2-ylidene)(Py)] catalysts

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorKaloglu, Murat
dc.contributor.authorSlimani, Ichraf
dc.contributor.authorOzdemir, Namik
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorHamdi, Naceur
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:50:32Z
dc.date.available2024-08-04T20:50:32Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, a series of air- and moisture-stable imidazolidin-2-ylidene-based new palladium complexes with the general formula [PdX2(NHC)(Py)] were synthesized (NHC = N-heterocyclic carbene, Py = pyridine, X = Cl or I). The structures of the palladium complexes were characterized by different techniques such as H-1 NMR, C-13 NMR, FT-IR spectroscopy and elemental analysis. The more detailed structural characterization of one of the palladium complex was determined by single-crystal X-ray diffraction study. The catalytic activities of all palladium complexes were tested in the direct arylation of five-membered aromatic N-heterocycles such as 3,5-dimethylisoxazole and 1-methyl-1H-pyrrole-2-carboxaldehyde with (hetero)aryl bromides in presence of 1 mol% catalyst loading at 120 degrees C. Desired products were obtained in moderate to good yields. (C) 2021 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [117R010]en_US
dc.description.sponsorshipThis study was supported by the Technological and Scientific Research Council of Turkey TUB. ITAK (Project No: 117R010).en_US
dc.identifier.doi10.1016/j.jorganchem.2021.122013
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85112399170en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2021.122013
dc.identifier.urihttps://hdl.handle.net/11616/100122
dc.identifier.volume951en_US
dc.identifier.wosWOS:000688430600002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladiumen_US
dc.subjectImidazolidin-2-ylideneen_US
dc.subjectPEPPSIen_US
dc.subjectC-H functionalizationen_US
dc.subjectN-Heterocyclesen_US
dc.titleThe direct C(sp2)-H functionalization and coupling of aromatic N-heterocycles with (hetero)aryl bromides by [PdX2(imidazolidin-2-ylidene)(Py)] catalystsen_US
dc.typeArticleen_US

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