Hydrolysis, polycondensation, and catalytic properties of Ru(II) complex of 3-4,5-dihydroimidazol-1-ylpropyltriethoxysilane

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorSeçkin, T
dc.contributor.authorÖzdemir, I
dc.contributor.authorÇetinkaya, B
dc.date.accessioned2024-08-04T20:12:19Z
dc.date.available2024-08-04T20:12:19Z
dc.date.issued2001
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe preparation and measurements of some properties of organic-inorganic hybrid materials derived from Ru(II)-3-4,5-dihyroimidazol-1-yl-propyltriethoxysilane inside a polysiloxane network have been achieved. The hydrolysis and polycondensation of Ru(II)-3-4,5-dihyroimidazol-1-yl-propyltriethoxysilane were performed in different experimental conditions, producing a new organic-inorganic silica. The alkoxysilyl groups available were used for the construction of inorganic backbone by the sal-gel process, and the imidazole group was found suitable for incorporating Ru(II) by coordination. The coordination of metal complex is retained because there is no leaching from the metal complex containing gels. To ensure sufficient catalytic properties, a series of hybrid materials from tetraethoxysilane was prepared. These materials were identified and catalytic activities were tested for cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol to 2,3-dimethylfuran. Heterogeneous Ru(II) catalyst can also be recycled and reused without significant loss of selectivity or activity. (C) 2001 John Wiley & Sons, Inc.en_US
dc.identifier.doi10.1002/app.1220
dc.identifier.endpage1334en_US
dc.identifier.issn0021-8995
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-0035938804en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1329en_US
dc.identifier.urihttps://doi.org/10.1002/app.1220
dc.identifier.urihttps://hdl.handle.net/11616/93357
dc.identifier.volume80en_US
dc.identifier.wosWOS:000167503200028en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectsol-gel processen_US
dc.subjectorganic-inorganic hybridsen_US
dc.subjectpolysiloxane networken_US
dc.subjectRu(II) complexen_US
dc.titleHydrolysis, polycondensation, and catalytic properties of Ru(II) complex of 3-4,5-dihydroimidazol-1-ylpropyltriethoxysilaneen_US
dc.typeArticleen_US

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