RUTHENIUM(II) COMPLEXES WITH CHELATING N-HETEROCYCLIC CARBENES AND A RUTHENATE(II) COMPLEX AS CATALYSTS FOR THE ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENE

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dc.contributor.authorYigit, Murat
dc.contributor.authorGok, Yetkin
dc.contributor.authorCelikal, Ozlem Ozeroglu
dc.contributor.authorYigit, Beyhan
dc.date.accessioned2024-08-04T20:50:36Z
dc.date.available2024-08-04T20:50:36Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew ruthenium chelate and ruthenate complexes were synthesized through the reaction of benzimidazolium salts and [RuCl2(p-cymene)](2) in toluene and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These ruthenium complexes were tested as catalysts in the intermolecular hydroamination reactions between styrene with aromatic amines in ionic liquid. All of these complexes tested here showed good catalytic activity in these reactions. The hydroamination reactions regioselectively produced anti-Markovnikov addition products in moderate to good yields by using 1 mol% of the ruthenium complex.en_US
dc.description.sponsorshipTurkish Research Council (TUBITAK) [107T419]en_US
dc.description.sponsorshipWe thank to Turkish Research Council (TUBITAK) (Project Number: 107T419) for financial support of this work.en_US
dc.identifier.doi10.3987/COM-21-14519
dc.identifier.endpage2137en_US
dc.identifier.issn0385-5414
dc.identifier.issn1881-0942
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-85113981145en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage2127en_US
dc.identifier.urihttps://doi.org/10.3987/COM-21-14519
dc.identifier.urihttps://hdl.handle.net/11616/100175
dc.identifier.volume102en_US
dc.identifier.wosWOS:000719567800004en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofHeterocyclesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectIntermolecular Hydroaminationen_US
dc.subjectC-Hen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectUnactivated Alkenesen_US
dc.subjectRu(Ii) Complexesen_US
dc.subjectOne-Poten_US
dc.subjectLigandsen_US
dc.subjectMetathesisen_US
dc.subjectAminesen_US
dc.subjectPrecursorsen_US
dc.titleRUTHENIUM(II) COMPLEXES WITH CHELATING N-HETEROCYCLIC CARBENES AND A RUTHENATE(II) COMPLEX AS CATALYSTS FOR THE ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENEen_US
dc.typeArticleen_US

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