Synthesis, characterization, and transfer hydrogenation of Ru(II)-N-heterocyclic carbene complexes

Basit Öğe Kaydı
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorYasar, S.
dc.contributor.authorCekirdek, S.
dc.contributor.authorOzdemir, I.
dc.date.accessioned2024-08-04T20:39:43Z
dc.date.available2024-08-04T20:39:43Z
dc.date.issued2014
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA new series of ruthenium(II) N-heterocyclic carbene complexes [RuL1,2,3(p-cymene)Cl-2] (3a-c) (where L is a N-heterocyclic carbene), have been synthesized via transmetalation. The new ruthenium( II)-NHC complexes were applied to transfer hydrogenation of acetophenone derivatives and aldehydes using 2-propanol as a hydrogen source and KOH as a co-catalyst. The results show that the corresponding alcohols could be obtained in good yield with high catalyst activity (up to 100%) under mild conditions. [RuL1(p-cymene)Cl-2] (3a) is much more active than the other complexes in transfer hydrogenation. Reactions, catalyzed by 3a-c, showed the highest reaction rates and yields of alcohol when the substrates bear more electron-withdrawing substituents. All new compounds were characterized by IR, elemental analysis, LC-MS (ESI), and NMR spectroscopy.en_US
dc.description.sponsorshipGaziosmanpasa University Research Fund [GOP. B.A.P: 2010/84, 2011/51, 2011/105]en_US
dc.description.sponsorshipThis work was financially supported by Gaziosmanpasa University Research Fund (GOP. B.A.P: 2010/84, 2011/51 and 2011/105).en_US
dc.identifier.doi10.1080/00958972.2014.911291
dc.identifier.endpage1248en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84901626848en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1236en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.911291
dc.identifier.urihttps://hdl.handle.net/11616/96465
dc.identifier.volume67en_US
dc.identifier.wosWOS:000337244100010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRutheniumen_US
dc.subjectSilveren_US
dc.subjectN-Heterocyclic carbineen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectTransmetalationen_US
dc.titleSynthesis, characterization, and transfer hydrogenation of Ru(II)-N-heterocyclic carbene complexesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu