Ruthenium(II)-(Arene)-N-Heterocyclic Carbene Complexes: Efficient and Selective Catalysts for the N-Alkylation of Aromatic Amines with Alcohols

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridACHARD, Mathieu/0000-0003-0578-9680
dc.authoridKaloglu, Nazan/0000-0003-3547-4209
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidACHARD, Mathieu/M-4916-2017
dc.contributor.authorKaloglu, Nazan
dc.contributor.authorAchard, Mathieu
dc.contributor.authorBruneau, Christian
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:00Z
dc.date.available2024-08-04T20:46:00Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of unsymmetrical 1,3-disubstituted benzimidazolium chlorides were synthesized as N-heterocyclic carbene (NHC) precursors. These compounds were used for synthesis of the new ruthenium(II) complexes of the type [RuCl2(arene)(NHC)], (arene = eta(6)-p-cymene). The structures of all compounds were characterized by H-1 NMR, C-13 NMR and FT-IR spectroscopy techniques. The catalytic activity of the ruthenium complexes has been evaluated with respect to the mono-N-alkylation reactions of aromatic amines with various alcohol derivatives under solvent-free conditions at 120 degrees C using the borrowing hydrogen strategy.en_US
dc.identifier.doi10.1002/ejic.201900191
dc.identifier.endpage2606en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issue21en_US
dc.identifier.scopus2-s2.0-85066930053en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2598en_US
dc.identifier.urihttps://doi.org/10.1002/ejic.201900191
dc.identifier.urihttps://hdl.handle.net/11616/98821
dc.identifier.wosWOS:000471072200005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCarbene ligandsen_US
dc.subjectRutheniumen_US
dc.subjectAromatic aminesen_US
dc.subjectHomogeneous catalysisen_US
dc.subjectAlkylationen_US
dc.subjectBorrowing hydrogen strategyen_US
dc.titleRuthenium(II)-(Arene)-N-Heterocyclic Carbene Complexes: Efficient and Selective Catalysts for the N-Alkylation of Aromatic Amines with Alcoholsen_US
dc.typeArticleen_US

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